1,3-diallyl amarine bromide | 881662-21-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1,3-diallyl amarine bromide
• CAS: 881662-21-1
• 化学式: Br*C₂₇H₂₇N₂
• 分子量: 459.429
• InChiKey: ZTGFYWREOFFOQM-AYEGBANISA-M

反应信息

• 作为反应物：
  描述：

  copper(I) bromide 、 1,3-diallyl amarine bromide 以 水 为溶剂， 以63.4%的产率得到[1,3-diallyl amarine]2[Cu2Br4]
  参考文献：
  名称：

  Crystal structures of amarine and isoamarine and copper(I) coordination chemistry with their allylation products

  摘要：

  The crystal structures of amarine (1) and isoamarine (2), important intermediates in the preparation of 1,2-diphenyl-diaminoethane, were successfully determined. Their allylation products, 1,3-diallyl amarine (1)(CH2-CH=CH2)(2)Br (3) and isoamarine bromide (2)(CH2-CH=CH2)(2)Br (4) [the crystal structures of (1)(CH2-CH=CH2)(2)PF6(3-Br + PF6) and (2)(CH2-CH=CH2)(2)PF6 (4-Br + PF6) are also successfully determined to confirm allylation products], react with CuBr to afford (1)(2)(CH2-CH=CH2)(4)(Cu2Br4) (5) and (2)(CH-CH=CH2)(2)(Cu2Br3) (6), respectively. Crystal structures of 5 and 6 reveal that 5 is an anion discrete complex without olefin moiety coordination, and 6 has a 1D infinite chain with olefin moiety coordination as a bridging spacer. The fluorescent emission spectra of 5 (lambda e(max) = 570 nm) and 6 (lambda(emax) = 642 nm) were measured, and display a significant difference that can be used for solid state fluorescent sensing them. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.10.040
• 作为产物：
  描述：

  3-溴丙烯 、 cis-2,4,5-triphenyl-2-imidazoline 在 sodium carbonate 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 以45%的产率得到1,3-diallyl amarine bromide
  参考文献：
  名称：

  Crystal structures of amarine and isoamarine and copper(I) coordination chemistry with their allylation products

  摘要：

  The crystal structures of amarine (1) and isoamarine (2), important intermediates in the preparation of 1,2-diphenyl-diaminoethane, were successfully determined. Their allylation products, 1,3-diallyl amarine (1)(CH2-CH=CH2)(2)Br (3) and isoamarine bromide (2)(CH2-CH=CH2)(2)Br (4) [the crystal structures of (1)(CH2-CH=CH2)(2)PF6(3-Br + PF6) and (2)(CH2-CH=CH2)(2)PF6 (4-Br + PF6) are also successfully determined to confirm allylation products], react with CuBr to afford (1)(2)(CH2-CH=CH2)(4)(Cu2Br4) (5) and (2)(CH-CH=CH2)(2)(Cu2Br3) (6), respectively. Crystal structures of 5 and 6 reveal that 5 is an anion discrete complex without olefin moiety coordination, and 6 has a 1D infinite chain with olefin moiety coordination as a bridging spacer. The fluorescent emission spectra of 5 (lambda e(max) = 570 nm) and 6 (lambda(emax) = 642 nm) were measured, and display a significant difference that can be used for solid state fluorescent sensing them. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.10.040