(1S,2S)-1-phenyl-1-(13-phosphapentacyclo[13.8.0.0^{2,11.0^{3,8.0^{18,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-yl)propan-2-amine | 1092064-04-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (1S,2S)-1-phenyl-1-(13-phosphapentacyclo[13.8.0.0^{2,11.0^{3,8.0^{18,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-yl)propan-2-amine
• 英文别名: 1-phenyl-1-(13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-yl)propan-2-amine
• CAS: 1092064-04-4
• 化学式: C₃₁H₂₈NP
• 分子量: 445.5
• InChiKey: BHRXRWRXVSJNML-UHFFFAOYSA-N

物化性质

• 熔点：
  >300°C
• 沸点：
  673.1±55.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  33
• 可旋转键数：
  3
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• PRACTICAL METHOD FOR REDUCING ESTERS OR LACTONES
  申请人：Tokyo Institute of Technology

  公开号：EP2298723A1

  公开（公告）日：2011-03-23

  Esters and lactones can be respectively reduced to alcohols and diols in the presence of the Group 8 (VIII) transition metal complex, base and hydrogen gas (H2). An extremely practical reduction method can be provided by preferable combinations of the Group 8 (VIII) transition metal complex, the base, a used amount of the base, a pressure of hydrogen gas and a reaction temperature. This method is used in place of hydride reduction and is a useful method by which design of highly active catalysts can be relatively easily made while a high productivity can be expected.

  在第 8 (VIII) 族过渡金属络合物、碱和氢气 (H2) 的存在下，酯和内酯可分别还原成醇和二元醇。8 (VIII)族过渡金属络合物、碱、碱的用量、氢气的压力和反应温度的最佳组合可以提供一种极为实用的还原方法。这种方法可代替氢化物还原法，是一种有用的方法，可以相对容易地设计出高活性催化剂，同时可望获得较高的生产率。
• Practical Method for Reducing Esters or Lactones
  申请人：Ikariya Takao

  公开号：US20110092747A1

  公开（公告）日：2011-04-21

  Esters and lactones can be respectively reduced to alcohols and diols in the presence of the Group 8 (VIII) transition metal complex, base and hydrogen gas (H 2 ). An extremely practical reduction method can be provided by preferable combinations of the Group 8 (VIII) transition metal complex, the base, a used amount of the base, a pressure of hydrogen gas and a reaction temperature. This method is used in place of hydride reduction and is a useful method by which design of highly active catalysts can be relatively easily made while a high productivity can be expected.
• US8344187B2
  申请人：——

  公开号：US8344187B2

  公开（公告）日：2013-01-01