pentakis(pentamethylene)hexamine | 104235-50-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: pentakis(pentamethylene)hexamine
• 英文别名: N'-[5-[5-[5-(5-aminopentylamino)pentylamino]pentylamino]pentyl]pentane-1,5-diamine
• CAS: 104235-50-9
• 化学式: C₂₅H₅₈N₆
• 分子量: 442.776
• InChiKey: VQEKUVUOSGOVPO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  31
• 可旋转键数：
  28
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  100
• 氢给体数：
  6
• 氢受体数：
  6

文献信息

• Lube oil compostitions for diesel engines
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0839894A1

  公开（公告）日：1998-05-06

  A lube oil composition which is suitably used for diesel engines which exhaust large amounts of sulfur dioxides (SOx). The composition exhibit excellent corrosion/wear preventive properties against SOx. The lube oil composition of the invention for diesel engines includes a lube oil base having a kinematic viscosity of 8-35 mm2/s at 100°C; a component (A) which is a compound selected from the group consisting of over based sulfonates of alkaline earth metals, over based phenates of alkaline earth metals, and over based salicylates of alkaline earth metals; and a component (B) which is a bis-type succinic imide compound having an absorption ratio, α/β (wherein α is the intensity of an absorption peak at 1550±10 cm-1 and β is the intensity of an absorption peak at 1700±10 cm-1), of absorption peaks in an IR spectrum of not more than 0.005.

  一种润滑油组合物，适用于排放大量二氧化硫（SOx）的柴油发动机。该组合物对 SOx 具有优异的防腐蚀/抗磨损性能。本发明用于柴油发动机的润滑油组合物包括：100°C 时运动粘度为 8-35 mm2/s 的润滑油基础；从碱土金属过基磺酸盐、碱土金属过基苯酸盐和碱土金属过基水杨酸盐所组成的组中选出的化合物成分 (A)；以及碱土金属过基苯酸盐和碱土金属过基水杨酸盐所组成的组中选出的化合物成分 (B)；成分 (B)是双型琥珀酰亚胺化合物，其在红外光谱中吸收峰的吸收比 α/β（其中 α 是 1550±10 cm-1 处吸收峰的强度，β 是 1700±10 cm-1 处吸收峰的强度）不超过 0。005.
• Novel succinimide compound and method for producing it, lubricating oil additive comprising the compound, and lubricating oil composition comprising the compound for diesel engines
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0839840A2

  公开（公告）日：1998-05-06

  Disclosed are novel succinimide compounds effective in diesel engine lubricating oil for protecting engine parts from being corroded or worn by SOx. An acid compound of formula (I) or (II) is reacted with a polyamine to produce the succinimide compounds, which give an absorption peak (α-peak) at 1640 ± cm-1 and an absorption peak (β-peak) at 1700 ± 10 cm-1 in the IR spectral pattern with the ratio, α-peak intensity/β-peak intensity, of being 0.12 or more. [1] R is an alkenyl or alkyl group derived from a C2 to C15 olefinic polymer and having a number-average molecular weight of from 200 to 4000. The succinimide compound is added to base oil along with a metallic detergent-dispersant additives selected from over-based sulfonates, phenates and salicylates of alkaline earth metals to give a lubricating oil composition for diesel engines.

  本发明公开了新型琥珀酰亚胺化合物，该化合物在柴油发动机润滑油中可有效保护发动机部件免受 SOx 的腐蚀或磨损。式（I）或（II）的酸化合物与多胺反应生成琥珀酰亚胺化合物，在红外光谱图中，琥珀酰亚胺化合物在 1640 ± cm-1 处有一个吸收峰（α-峰），在 1700 ± 10 cm-1 处有一个吸收峰（β-峰），α-峰强度/β-峰强度之比为 0.12 或以上。 [1] R 是烯基或烷基，由 C2 至 C15 烯烃聚合物衍生而来，平均分子量为 200 至 4000。将琥珀酰亚胺化合物与选自碱土金属过基磺酸盐、苯酸盐和水杨酸盐的金属清净分散剂添加剂一起加入基础油中，可得到用于柴油发动机的润滑油组合物。
• FUEL OIL ADDITIVE AND FUEL OIL COMPOSITION
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP1116779A1

  公开（公告）日：2001-07-18

  Provided are a fuel oil additive comprising (a) an alkenylsuccinimide or alkylsuccinimide compound or its boron adduct, (b) a lubricant, and optionally (c) a low-temperature fluidability improver, and having a temperature per 90% recovered with distillation of 320°C or higher; and a fuel oil composition comprising fuel oil and the additive added thereto. The additive has excellent capabilities to enhance the lubricity in fuel injection pumps and to enhance the detergency in fuel injection nozzles, and it is especially favorable to low-sulfur gas oil.

  本发明提供了一种燃料油添加剂，该添加剂包含（a）烯基琥珀酰亚胺或烯基琥珀酰亚胺化合物或其硼加合物，（b）润滑剂，以及可选的（c）低温流动性改进剂，其蒸馏回收率为 90% 的温度为 320°C 或更高；以及一种燃料油组合物，该组合物包含燃料油和添加到其中的添加剂。该添加剂在增强燃料喷射泵的润滑性和增强燃料喷射喷嘴的清净性方面具有出色的性能，尤其适用于低硫天然气油。
• LUBRICATING OIL COMPOSITION FOR INTERNAL COMBUSTION ENGINE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1829952A1

  公开（公告）日：2007-09-05

  The present invention provides a lubricating oil composition comprising a lube base oil comprising a mineral oil and/or a synthetic oil; (A) an alkenylsuccinimide or an alkylsuccinimide and/or a boron-containing derivative thereof in an amount of 0.01 to 0.14 % by mass based on the composition in terms of the nitrogen content as an ashless dispersant, wherein an alkenylsuccic acid monoimide or an alkylsuccinic acid monoimide and/or a boron-containing derivative thereof in the ashless dispersant is 0.05 % by mass or less in terms of nitrogen content; and (B) a dialkyldiphenylamine compound in an amount of 0.3 to 5.0 % by mass and a hindered phenol compound in an amount of 0 to 2.5 % by mass based on the composition as an antioxidant, and (C) a sulfated ash of the lubricating oil composition is 1.2 % by mass or less. The lubricating oil composition suitable for internal combustion engines has excellent oxidation stability despite low ash content, exhibits small increase in viscosity and acid number, and can prolong the interval (distance or time) required for changing lubricating oil.

  本发明提供了一种润滑油组合物，该组合物包含由矿物油和/或合成油组成的润滑油基础油；(A) 烷基琥珀酰亚胺或烷基琥珀酰亚胺和/或其含硼衍生物，作为无灰分散剂，其用量为组合物中氮含量的 0.(A) 烷基琥珀酰亚胺或烷基琥珀酰亚胺和/或其含硼衍生物，以氮含量计，其质量百分比为 0.01 至 0.14%，作为无灰分散剂，其中烷基琥珀酸单亚胺或烷基琥珀酸单亚胺和/或其含硼衍生物在无灰分散剂中的质量百分比为 0.(B) 作为抗氧化剂的二烷基二苯胺化合物的质量分数为 0.3 至 5.0 %，受阻酚化合物的质量分数为 0 至 2.5 %，以及 (C) 润滑油组合物的硫酸盐灰分的质量分数为 1.2 % 或以下。 适用于内燃机的润滑油组合物尽管灰分含量低，但却具有极佳的氧化稳定性，粘度和酸数的增加很小，并能延长更换润滑油所需的间隔（距离或时间）。
• LUBRICANT COMPOSITION FOR INTERNAL COMBUSTION ENGINE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP2060619A1

  公开（公告）日：2009-05-20

  A lubricating oil composition for internal combustion engines, containing a base oil, (A) at least one compound selected from disulfide compounds represented by the following general formula (I):         R1OOC-A1-S-S-A2-COOR2     (I) and disulfide compounds represented by the following general formula (II):         R7OOC-CR9R10-CR11(COOR8)-S-S-CR16(COOR13)-CR14R15-COOR12     (II), (B) an organomolybdenum compound, and (C) a phenol-based antioxidant and/or an amine-based antioxidant. The lubricating oil composition is a low ash, low phosphorus lubricating oil composition which is used for internal combustion engines such as gasoline engines, diesel engines and gas engines, which has improved oxidation stability and friction reducing effect, and which complies with environmental regulations.

  一种用于内燃机的润滑油组合物，含有基础油、(A) 至少一种选自以下通式 (I) 所代表的二硫化物的化合物： R1OOC-A1-S-A2-COR2 (I) 和以下通式 (II) 所代表的二硫化物： R7OOC-CR9R10-CR11(COOR8)-S-S-CR16(COOR13)-CR14R15-COR12 (II)、 (B) 有机钼化合物，以及 (C) 苯酚基抗氧化剂和/或胺基抗氧化剂。该润滑油组合物是一种低灰、低磷润滑油组合物，可用于汽油发动机、柴油发动机和燃气发动机等内燃机，具有更好的氧化稳定性和减摩效果，并且符合环保法规。