| 928160-45-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 928160-45-6
• 化学式: C₄₄H₃₆O₁₀
• 分子量: 724.764
• InChiKey: QWZXVVOYULUGHP-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  在 RuCl2(1,3-dimesityl-imidazolidin-2-yl)(PCy3)(=CHPh) 作用下， 以 苯 为溶剂， 反应 2.0h， 生成 、
  参考文献：
  名称：

  Rapid atropisomerization of 1,1′:5′,1″-ternaphthalene-2,2′,6′,2″-tetrol (TERNOL) and its inhibition by tethering at positions 7 and 7″

  摘要：

  Atropisomerization of 1,1':5',1"-temaphthalene-2,2',6',2"-tetrol (TERNOL) is very fast under basic conditions. The stereochemical instability is attributed to the nature of oxide anion of the central 2,6-naphthodiol moiety. Ring-closing metathesis of 7,7"-diallyloxy TERNOL results in intramolecular tethering in a high yield, which intrinsically inhibits the rapid isomerization. Bidentate sites in the tethered TERNOL are proved to have enough structural flexibility as an axial chiral ligand. (c) 2006 Elsevier Ltd, All rights reserved.

  DOI：

  10.1016/j.tet.2006.12.046
• 作为产物：
  描述：

  1,5-Bis(2-hydroxy-7-prop-2-enoxynaphthalen-1-yl)naphthalene-2,6-diol 、 乙酸酐 在 吡啶 作用下， 以96%的产率得到
  参考文献：
  名称：

  Rapid atropisomerization of 1,1′:5′,1″-ternaphthalene-2,2′,6′,2″-tetrol (TERNOL) and its inhibition by tethering at positions 7 and 7″

  摘要：

  Atropisomerization of 1,1':5',1"-temaphthalene-2,2',6',2"-tetrol (TERNOL) is very fast under basic conditions. The stereochemical instability is attributed to the nature of oxide anion of the central 2,6-naphthodiol moiety. Ring-closing metathesis of 7,7"-diallyloxy TERNOL results in intramolecular tethering in a high yield, which intrinsically inhibits the rapid isomerization. Bidentate sites in the tethered TERNOL are proved to have enough structural flexibility as an axial chiral ligand. (c) 2006 Elsevier Ltd, All rights reserved.

  DOI：

  10.1016/j.tet.2006.12.046