| 150147-93-6

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 均质其他非金属化合物
• CAS: 150147-93-6
• 化学式: FH*N₂
• 分子量: 49.0118
• InChiKey: OJEOJDCACCMHBH-DYCDLGHISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.18
• 重原子数：
  3.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  47.58
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  氟化氘 、 氘 以 solid matrix 为溶剂， 生成 deuterium fluoride dimer 、 hydrogen fluoride trimer 、 、 、 deuterium-deuterium fluoride dimer
  参考文献：
  名称：

  Infrared spectra of the very weak H₂‐‐HF and O₂‐‐HF complexes in solid neon

  摘要：

  Very weak, hydrogen bonded complexes of molecular hydrogen and oxygen with HF have been prepared by condensing the neon diluted reagents at 4–5 K. Infrared spectra of the H2--HF complex revealed a νs(HF) mode at 3938 cm−1 and νc(H2) mode at 4155 cm−1 which are red shifted from isolated molecule values in agreement with theoretical predictions. Increasing the HF concentration produced a 1:2 complex, H2–(HF)2. Similar experimental results were obtained for molecular oxygen complexes using HF and DF; the oxygen fundamental in this complex, however, exhibited a 6 cm−1 blue shift. Spectra of these complexes in argon matrices showed that argon is not an effectively inert medium for very weak complexes where interaction with the solid argon environment is competitive with the H2–HF and O2–HF interactions.

  DOI：

  10.1063/1.451934