[Cu(3,3'-iminobispropylamine)(tetracyanopalladate)]n | 949156-58-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [Cu(3,3'-iminobispropylamine)(tetracyanopalladate)]n
• CAS: 949156-58-5
• 化学式: C₁₀H₁₇CuN₇Pd
• 分子量: 405.258
• InChiKey: FUBJZAOJDKXTRN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 3,3'-二氨基二丙基胺 、 potassium tetracyanopalladate(II) monohydrate 以 甲醇 、 水 为溶剂， 以80%的产率得到[Cu(3,3'-iminobispropylamine)(tetracyanopalladate)]n
  参考文献：
  名称：

  Hetero-metallic frameworks of [Pd(CN)4]2− and Cu(II) with triamines: A rare example of a tetracyanometallate bridged 2D coordination polymer

  摘要：

  Four cyano bridged Cu(II)-Pd(II) heterometallic complexes, [Cu(dpt)Pd(CN)(4)](n) (1), {[Cu-2(medpt)(2)Pd(CN)(4)](ClO4)(2) center dot 3H(2)O}(n) (2), {[Cu-2(dien)(2)Pd(CN)(4)](ClO4)(2)center dot 2CH(3)OH}(n) (3) and {[Cu-2(iPrdien)(2)Pd(CN)(4)](ClO4)(2)center dot 2H(2)O}(n) (4) [dpt=3,3'-iminobispropylamine; medpt = 3,3'-diamino-N-methyldipropylamine; dien = diethylenetriamine and iprdien = N'-isopropyldiethylenetriamine] have been synthesized and characterized by single crystal X-ray diffraction analysis, magnetic measurement and thermal study. Complexes 1, 2 and 3 are ID coordination polymers, while 4 presents a 2D network. In 1, the cis-directed cyanide ligands of [Pd(CN)(4)](2-) anions link two Cu(dpt) units to form a neutral coordination polymer, whereas in 2, 3 and 4, all the cyanide groups of [Pd(CN)(4)](2-) take part in bonding with four adjacent Cu(II) ions, resulting in cationic coordination polymers counterbalanced by perchlorate anions. The structures are compared with those of analogous [Ni(CN)(4)](2-) derivatives. The magnetic behavior shows antiferromagnetic interactions in all the complexes. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.02.028