7-bromo-2-phenylnaphthalen-1-ol | 1354728-01-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 7-bromo-2-phenylnaphthalen-1-ol
• CAS: 1354728-01-0
• 化学式: C₁₆H₁₁BrO
• 分子量: 299.167
• InChiKey: KBEZKROGQIOWCQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  7-bromo-2-hydroxy-2-phenyl-3,4-dihydronaphthalen-1(2H)-one 在 对甲苯磺酸 作用下， 以 甲苯 为溶剂， 反应 12.0h， 以81%的产率得到7-bromo-2-phenylnaphthalen-1-ol
  参考文献：
  名称：

  Synthesis of substituted α-tetralones and substituted 1-naphthols via regioselective ring expansion of 1-acyl-1-indanol skeleton

  摘要：

  Substituted 1-acyl-1-indanols were prepared using the corresponding readily commercially available substituted indanones as starting materials. Treatment of each 1-acyl-1-indanol derivative with sodium methoxide in hot methanol furnished a regiospecific 2-hydroxy-alpha-tetralone derivative, which was an alpha-keto rearrangement product. Each substituted 2-hydroxy-alpha-tetralone then underwent dehydration to afford the corresponding 1-naphthol derivative. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.11.103

文献信息

• COMPOUND FOR ORGANIC ELECTRIC ELEMENT, ORGANIC ELECTRIC ELEMENT USING SAME, AND ELECTRONIC DEVICE THEREFOR
  申请人：Duk San Neolux Co., Ltd.

  公开号：EP3305773A1

  公开（公告）日：2018-04-11

  Provided are a compound represented by Formula 1, and an organic electric element comprising a first electrode, a second electrode, and an organic material layer formed between the first electrode and the second electrode, wherein the organic material layer comprised the compound represented by Formula 1, and the driving voltage of an organic electronic device can be lowered, and the luminous efficiency, color purity and life time of an organic electronic device can be improved by comprising the compound represented by Formula 1 in the organic material layer.

  提供了一种式 1 所代表的化合物，以及一种有机电子元件，该元件包括第一电极、第二电极以及形成于第一电极和第二电极之间的有机材料层，其中有机材料层包括式 1 所代表的化合物，通过在有机材料层中包含式 1 所代表的化合物，可以降低有机电子设备的驱动电压，并提高有机电子设备的发光效率、色彩纯度和使用寿命。
• Compound for organic electric element, organic electric element comprising the same and electronic device thereof
  申请人：DUK SAN NEOLUX CO., LTD.

  公开号：US11380846B2

  公开（公告）日：2022-07-05

  Provided are a compound represented by Formula 1, and an organic electric element comprising a first electrode, a second electrode, and an organic material layer formed between the first electrode and the second electrode, wherein the organic material layer comprised the compound represented by Formula 1, and the driving voltage of an organic electronic device can be lowered, and the luminous efficiency, color purity and life time of an organic electronic device can be improved by comprising the compound represented by Formula 1 in the organic material layer.

  提供了一种式 1 所代表的化合物，以及一种有机电子元件，该元件包括第一电极、第二电极以及形成于第一电极和第二电极之间的有机材料层，其中有机材料层包括式 1 所代表的化合物，通过在有机材料层中包含式 1 所代表的化合物，可以降低有机电子设备的驱动电压，并提高有机电子设备的发光效率、色彩纯度和使用寿命。
• COMPOUND FOR ORGANIC ELECTRIC ELEMENT, ORGANIC ELECTRIC ELEMENT COMPRISING THE SAME AND ELECTRONIC DEVICE THEREOF
  申请人：DUK SAN NEOLUX CO., LTD.

  公开号：US20180083197A1

  公开（公告）日：2018-03-22

  Provided are a compound represented by Formula 1, and an organic electric element comprising a first electrode, a second electrode, and an organic material layer formed between the first electrode and the second electrode, wherein the organic material layer comprised the compound represented by Formula 1, and the driving voltage of an organic electronic device can be lowered, and the luminous efficiency, color purity and life time of an organic electronic device can be improved by comprising the compound represented by Formula 1 in the organic material layer.
• [EN] COMPOUND FOR ORGANIC ELECTRIC ELEMENT, ORGANIC ELECTRIC ELEMENT USING SAME, AND ELECTRONIC DEVICE THEREFOR<br/>[FR] COMPOSÉ POUR ÉLÉMENT ÉLECTRIQUE ORGANIQUE, ÉLÉMENT ÉLECTRIQUE ORGANIQUE UTILISANT CE COMPOSÉ, ET DISPOSITIF ÉLECTRONIQUE CORRESPONDANT<br/>[KO] 유기전기 소자용 화합물, 이를 이용한 유기전기소자 및 그 전자 장치
  申请人：DUK SAN NEOLUXCO LTD

  公开号：WO2016190600A1

  公开（公告）日：2016-12-01

  본 발명은 화학식 1로 표시되는 화합물을 제공한다. 또한, 제 1전극, 제 2전극 및 상기 제 1전극과 상기 제 2전극 사이의 유기물층을 포함하는 유기전기소자를 제공하며, 상기 유기물층은 화학식 1로 표시되는 화합물을 포함한다. 유기전기소자의 유기물층에 화학식 1로 표시되는 화합물이 포함되면, 구동전압을 낮출 수 있고, 발광효율, 색순도 및 수명 등을 향상시킬 수 있다.
• Synthesis of substituted α-tetralones and substituted 1-naphthols via regioselective ring expansion of 1-acyl-1-indanol skeleton
  作者：Te-Fang Yang、Kuan-Yu Wang、Hsuan-Wei Li、Yang-Chan Tseng、Tai-Chen Lien

  DOI：10.1016/j.tetlet.2011.11.103

  日期：2012.2

  Substituted 1-acyl-1-indanols were prepared using the corresponding readily commercially available substituted indanones as starting materials. Treatment of each 1-acyl-1-indanol derivative with sodium methoxide in hot methanol furnished a regiospecific 2-hydroxy-alpha-tetralone derivative, which was an alpha-keto rearrangement product. Each substituted 2-hydroxy-alpha-tetralone then underwent dehydration to afford the corresponding 1-naphthol derivative. (C) 2011 Elsevier Ltd. All rights reserved.