cis-3-aminohexahydroazepinediiodoplatinum(II) | 157641-95-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: cis-3-aminohexahydroazepinediiodoplatinum(II)
• CAS: 157641-95-7
• 化学式: C₆H₁₄I₂N₂Pt
• 分子量: 563.08
• InChiKey: NPWCHCDRTZGPRW-GSUNZCPGSA-L

反应信息

• 作为反应物：
  描述：

  cis-3-aminohexahydroazepinediiodoplatinum(II) 、 barium isopropylidenemalonate dihydrate 、 silver sulfate 以 水 为溶剂， 以71%的产率得到cis-3-aminohexahydroazepine(isopropylidenemalonato)platinum(II)
  参考文献：
  名称：

  Synthesis and structural properties of ylidenemalonatoplatinum(II) complexes

  摘要：

  New platinum(II) complexes A2Pt(OOC)2C=CR2 (1, A2 = 3-aminohexahydroazepine, R2 = -(CH2)5-; 2, A2 = 3-aminohexahydroazepine, R = CH3; 3, A2 = 3-aminohexahydroazepine, R2 = -SCH2CH2S-; 4, A = cyclopropylamine, R2 = -SCH2CH2 S-) have been prepared and characterized. The molecular structures of the representative complexes 1-2H2O and 4.C3H7NO were determined by X-ray analysis. The platinum atoms for 1-2H2O and 4.C3H7NO achieve a typical square planar arrangement with each nitrogen atom in cis position. For 1.2H2O an unusually short C=C bond [ 1. 298(18) angstrom] has been observed in contrast to the corresponding bond [1.374(9) angstrom] in 4.C3H7NO. The spectroscopic and physicochemical data disclose that these platinum complexes are stable and their molecular structures are retained in aqueous solution.

  DOI：

  10.1016/s0277-5387(00)81706-4