| 132850-97-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• CAS: 132850-97-6
• 化学式: C₁₆H₃₆Cl₂O₄P₂Pt₂
• 分子量: 815.473
• InChiKey: CUCQYQNMTWUANR-UHFFFAOYSA-J

反应信息

• 作为反应物：
  描述：

  吡唑 、 以 二氯甲烷 为溶剂， 以57%的产率得到{Pt2Cl2(μ-pyrazolato)2(PEt3)2}
  参考文献：
  名称：

  Binuclear pyrazolato-bridged platinum(II) complexes: synthesis, characterization and crystal structure

  摘要：

  Binuclear pyrazolato-bridged platinum(II) complexes of the type [Pt2Cl2(mu-L-L)2(PR3)2] [L-L = pz (pyrazolate) or dmpz (3,5-dimethylpyrazolate); PR3 = PEt3, PMe2Ph or PMePh2] have been prepared by the reaction of [Pt2Cl2(mu-O2CMe)2(PR3)2] with Hpz or Hdmpz. All the complexes were characterized by elemental analysis and H-1 and P-31 NMR data. A single-crystal structure analysis of a representative complex, [Pt2Cl2(mu-dmpz)2(PMePh2)2], is also reported. Crystals are orthorhombic, with space group Pbca and unit-cell dimensions a = 17.701 (9), b = 24.906(8), c = 16.976(7) angstrom. The structure was refined to final R = 0.040 for 3857 reflections with / greater-than-or-equal-to 3.0sigma(/).

  DOI：

  10.1039/dt9930003625