Cu(1-(α-aminobenzyl)-2-naptholato)2 | 108037-80-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: Cu(1-(α-aminobenzyl)-2-naptholato)2
• CAS: 108037-80-5；1363727-92-7；1363727-97-2；1363728-47-5
• 化学式: C₃₄H₂₈CuN₂O₂
• 分子量: 560.155
• InChiKey: FHVLGSRHZKLFNR-NCTGSHGJSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 (±)-1-(α-aminobenzyl)-2-naphthol 以 甲醇 为溶剂， 以68.7%的产率得到Cu(1-(α-aminobenzyl)-2-naptholato)2
  参考文献：
  名称：

  Synthesis and characterization of some novel copper(II) complexes with an optically active Betti base

  摘要：

  Novel Cu(II) complexes with racemic as well as optically pure 1-(alpha-amino benzyl)-2-napthol, commonly known as Betti base, and its derivative 1-(alpha-pyrrolidinyl benzyl)-2-napthol have been synthesized. The general composition of all the isolated complexes, as determined by elemental analysis, thermal analysis and FAB mass spectra, is found to be Cu(L-H)(2). The coordination of the ligand with metal has been confirmed by IR and ESR spectra of the complexes. The CD spectra of complexes with the S-form of the ligands exhibit a mirror image relationship with the CD spectra of the complexes with the corresponding R-form of the ligands. The Cu(II) complex with racemic Betti base has been characterized structurally. It crystallizes in the monoclinic space group P2(1)/c. The complexes display quasi reversible redox behavior due to the Cu(II)/Cu(I) reduction process. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.12.034