bis(phenylthio)bis(tributyl-l5-phosphaneyl)cobalt | 149272-27-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(phenylthio)bis(tributyl-l5-phosphaneyl)cobalt
• CAS: 149272-27-5
• 化学式: C₃₆H₆₄CoP₂S₂
• 分子量: 681.977
• InChiKey: XOFCUDZRPCNMSC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  14.22
• 重原子数：
  41.0
• 可旋转键数：
  24.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  三丁基膦 、 sodium thiophenolate 、 cobalt(II) chloride 以 乙腈 为溶剂， 以53%的产率得到bis(phenylthio)bis(tributyl-l5-phosphaneyl)cobalt
  参考文献：
  名称：

  Cobalt complexes with pnicogen (phosphine or pyridine) and thiolato ligands. Syntheses, x-ray crystal structures and spectroscopic characterization

  摘要：

  Mixed pnicogen and thiolato mononuclear cobalt complexes, CO(SR)2(PBun3)2 [R = Ph (1); R = Stolyl-p (2)] and Co(mpo)2L [L = PBun3 (3); L = Py (4)], have been synthesized and studied spectroscopically. The complexes 1 and 2 are tetrahedral, as determined by magnetic susceptibility studies. The structures of 3 and 4 were determined by X-ray diffraction. The cobalt(II) ions in both 3 and 4 are in a square-pyramidal environment with the two trans-oriented mpo ligands in the basal plane and the pnicogen group in the axial position.

  DOI：

  10.1016/s0277-5387(00)81539-9