[Ru(μ-Cl)(Cl)(CO)2(detp)]2 | 866358-59-0

• 英文名称: [Ru(μ-Cl)(Cl)(CO)2(detp)]2
• 英文别名: [Ru(μ-Cl)Cl(CO)2(bis[2-(ethyl)phenyl]-(phenyl) phosphane)]2
• CAS: 866358-59-0
• 化学式: C₄₈H₄₆Cl₄O₄P₂Ru₂
• 分子量: 1092.79
• InChiKey: IQJVERKYYDOEQT-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [RuCl2(CO)3(detp)] 、 Di-(2-ethylphenyl)-phenyl-phosphin 以 乙醇 为溶剂， 生成 [Ru(μ-Cl)(Cl)(CO)2(detp)]2
  参考文献：
  名称：

  Synthesis, characterization, reactivity and theoretical studies of ruthenium carbonyl complexes containing ortho-substituted triphenyl phosphanes

  摘要：

  A series of ruthenium o-phosphane complexes was synthesized and characterized. The reactivity of the prepared complexes was studied by using them as catalysts for the hydroformylation of 1-hexene. The activities depended on the binding mode of the phosphane and on the strength of the ruthenium-phosphane interaction. Strongly coordinated chelating [2-(dimethylamino)phenyl]-(diphenyl) phosphane and [2-(methylthio)phenyl]-(diphenyl) phosphane showed poor activity, while weakly chelated [2-(methoxy)phenyl]-(diphenyl) phosphane and non-chelating phosphanes such as [2-(methyl)phenyl]-(diphenyl) phosphane or [2-(ethyl)phenyl]-(diphenyl) phosphane led to higher activities. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.05.016