Salicylaldehyd-<2-hydroxynaphthyl-(1)-methyl-imid> | 88855-84-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: Salicylaldehyd-<2-hydroxynaphthyl-(1)-methyl-imid>
• 英文别名: N-(2-hydroxy-1-naphthylmethyl)salicylaldimine；salicylidene-(2-hydroxy-1-naphthylmethylamine)；salicylaldehyde-(2-hydroxy-[1]naphthylmethylimine)；Salicylaldehyd-(2-hydroxy-[1]naphthylmethylimin)；1-[[(2-Hydroxyphenyl)methylideneamino]methyl]naphthalen-2-ol
• CAS: 88855-84-9
• 化学式: C₁₈H₁₅NO₂
• 分子量: 277.323
• InChiKey: HVVBDJQCBOFKMR-UHFFFAOYSA-N

物化性质

• 熔点：
  175-177 °C(Solv: isopropyl ether (108-20-3); ethyl acetate (141-78-6))
• 沸点：
  493.8±35.0 °C(Predicted)
• 密度：
  1.17±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  52.8
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Salicylaldehyd-<2-hydroxynaphthyl-(1)-methyl-imid> 在 pyridine 作用下， 以 吡啶 为溶剂， 生成
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B4, 167, page 1817 - 1819

  摘要：

  DOI：
• 作为产物：
  描述：

  2-羟基萘-1-甲胺 、 水杨醛 生成 Salicylaldehyd-<2-hydroxynaphthyl-(1)-methyl-imid>
  参考文献：
  名称：

  Dikmen; Guenduez, Chemische Berichte, 1956, vol. 89, p. 2637,2639

  摘要：

  DOI：

文献信息

• Dikmen, C.; Guenduez, T., Chemische Berichte, 1956, vol. 89, p. 2637 - 2641
  作者：Dikmen, C.、Guenduez, T.

  DOI：——

  日期：——
• Some complexes of Nickel(II) with Ono Type Schiff Bases and their Monoligand Adducts. Part II.
  作者：Orhan Atakol、Adnan Kenar、Mehmet Kabak

  DOI：10.1080/00945719708000179

  日期：1997.1

  Coordination compounds of Ni(II) with four ONO-type Schiff bases, namely, N-2-hydroxybenzylsalicylaldimine (I), N-2-hydroxy-1-naphthylmethylsalicylaldimine (II), N-2-hydroxybenzyl-2-hydroxy-1-naphthaldimine (III) and N-2-hydroxy-1-naphthylmethyl-2-hydroxy-1-naphthaldimine (IV) have been studied. The ligands (III) and (IV) were found to form complexes of the composition NiL(2) (where L represents the Schiff base). The Ni(II) complexes of Schiff bases (I) and (II) were not obtained in crystalline form. In the presence of n-butylamine, however, all Schiff bases formed Ni(II) complexes of the composition NiL'(2), where L' represents Schiff bases formed by an amine exchange between L and n-butylamine. Furthermore, in the presence of piperidine, (I), (II), (III) and (IV) gave complexes of the composition NiLL '', (L '' is piperidine). Since all the complexes are diamagnetic, the coordination of Ni(II) was considered to be square-planar.
• Havinale, B. R.; Pujar, I. B., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1985, vol. 24, # 12, p. 1042 - 1045
  作者：Havinale, B. R.、Pujar, I. B.

  DOI：——

  日期：——
• Havinale, B. R.; Pujar, I. B., Journal of the Indian Chemical Society, 1988, vol. 65, # 10, p. 710 - 712
  作者：Havinale, B. R.、Pujar, I. B.

  DOI：——

  日期：——
• Havinale, B. R.; Pujar, I. B., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1981, vol. 20, # 11, p. 1130 - 1132
  作者：Havinale, B. R.、Pujar, I. B.

  DOI：——

  日期：——