4,5,6,7-四甲基-2,1,3-苯并噻二唑 | 106148-64-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻二唑类
• 中文名称: 4,5,6,7-四甲基-2,1,3-苯并噻二唑
• 英文名称: 4,5,6,7-tetramethylbenzo-2,1,3-thiadiazole
• 英文别名: 4,5,6,7-Tetramethyl-2,1,3-benzothiadiazole
• CAS: 106148-64-5
• 化学式: C₁₀H₁₂N₂S
• mdl: MFCD00785103
• 分子量: 192.285
• InChiKey: SPDOODVVIKUTCF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  54
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4,7-di(chloromethyl)-5,6-dimethylbenzo-2,1,3-thiadiazole 在 吡啶 、 盐酸 、 氯化亚砜 、 tin(ll) chloride 作用下， 以 乙醇 为溶剂， 反应 28.0h， 生成 4,5,6,7-四甲基-2,1,3-苯并噻二唑
  参考文献：
  名称：

  D'yachenko, E. K.; Pesin, V. G.; Papirnik, M. P., Journal of Organic Chemistry USSR (English Translation), 1986, vol. 22, p. 372 - 375

  摘要：

  DOI：

文献信息

• ANTHRACENE-BASED ORGANIC DYE
  申请人：National Chi Nan University

  公开号：US20180155549A1

  公开（公告）日：2018-06-07

  Disclosed herein is an anthracene-based organic dye represented by Formula (1): wherein the substituents contained in Formula (1) are as defined herein. The anthracene-based organic dye may be used as a photosensitizer in dye-sensitized solar cells to effectively absorb light having a wavelength range which covers the entire visible light wavelength range and which even expands to a near infrared wavelength range and convert the absorbed light into photoelectric current.

  本文公开了一种以蒽为基础的有机染料，其化学式如下所示： 其中，化学式（1）中包含的取代基如本文所定义。这种以蒽为基础的有机染料可以作为染料敏化太阳能电池中的光敏剂，有效吸收包括整个可见光波长范围在内甚至扩展至近红外波长范围的光，并将吸收的光转化为光电流。
• FUSED THIOPHENE DITIN MONOMERS
  申请人：Corning Incorporated

  公开号：US20150065722A1

  公开（公告）日：2015-03-05

  The disclosure relates to thiophene-based ditin compounds and methods of making and using such compounds. The disclosed compounds are novel structures having organotin groups on a conjugated aryl group spaced from and adjacent to a fused thiophene moiety. The formation of trialkyl tin groups spaced away from the fused thiophene moieties is advantageous in that it allows for novel polymerization via Stille coupling.

  该披露涉及基于噻吩的二锡化合物及其制备和使用方法。所披露的化合物是具有有机锡基团的新型结构，该有机锡基团位于共轭芳基上，与融合的噻吩基团相隔一定距离且相邻。远离融合的噻吩基团形成三烷基锡基团的优点在于，它允许通过Stille偶联进行新型聚合。
• POLYMER COMPOUND AND POLYMER LIGHT EMITTING DEVICE
  申请人：Nakatani Tomoya

  公开号：US20090302748A1

  公开（公告）日：2009-12-10

  A polymer compound comprising repeating units of the following formulae (I), (II) and (III): (wherein, R 1 and R 2 represent a hydrogen atom, alkyl group, alkoxy group or the like, R 3 and R 4 represent an alkyl group, alkoxy group or the like, and a and b represent 0 to 3, and the like.) (wherein, R N1 represents an alkyl group, R 5 and R 6 represent an alkyl group, alkoxy group or the like, and c and d represent 0 to 3.) AR  (III) (wherein, Ar represents a divalent condensed polycyclic hydrocarbon group or the like).

  一种聚合物化合物，包括以下式子（I），（II）和（III）的重复单元：（其中，R1和R2代表氢原子，烷基，烷氧基或类似物，R3和R4代表烷基，烷氧基或类似物，a和b代表0到3等。）（其中，RN1代表烷基，R5和R6代表烷基，烷氧基或类似物，c和d代表0到3。）（III）（其中，Ar代表双价缩合多环碳氢基团或类似物）。
• POLYMER COMPOUND AND LIGHT-EMITTING DEVICE USING SAME
  申请人：Fukushima Daisuke

  公开号：US20120326140A1

  公开（公告）日：2012-12-27

  It is an object of the invention to provide a polymer compound that, when used in a light-emitting device, results in excellent luminance life for the obtained light-emitting device. The invention provides a polymer compound comprising a constitutional unit represented by formula (1). [In formula (1), R 1A , R 1B , R 2A , R 2B represent an unsubstituted alkyl group, R 3 and R 4 represented an unsubstituted or substituted alkyl group, an unsubstituted or substituted alkoxy group, an unsubstituted or substituted aryl group, an unsubstituted or substituted aryloxy group, an unsubstituted or substituted heterocyclic group, an unsubstituted or substituted silyl group, a halogen atom, an alkoxycarbonyl group, a carboxyl or a cyano group, and R 5 and R 6 represent an unsubstituted or substituted alkyl group, an unsubstituted or substituted alkoxy group or an unsubstituted or substituted aryl group. The letters a, b, c and d each represent an integer of 0 to 3. When multiple R 3 , R 4 , R 5 and R 6 groups are present, they may be the same or different.]

  本发明的目的是提供一种聚合物化合物，当用于发光装置时，能够为所获得的发光装置提供优异的亮度寿命。该发明提供了一种聚合物化合物，其包含由式（1）表示的构成单元。[在式（1）中，R1A、R1B、R2A、R2B表示未取代的烷基，R3和R4表示未取代或取代的烷基，未取代或取代的烷氧基，未取代或取代的芳基，未取代或取代的芳氧基，未取代或取代的杂环基，未取代或取代的硅基，卤素原子，烷氧羰基，羧基或氰基，R5和R6表示未取代或取代的烷基，未取代或取代的烷氧基或未取代或取代的芳基。字母a、b、c和d分别表示0到3的整数。当存在多个R3、R4、R5和R6基团时，它们可以相同或不同。]
• Novel Photoactive Polymers
  申请人：Merck Patent GmbH

  公开号：US20140053905A1

  公开（公告）日：2014-02-27

  This disclosure relates to a photovoltaic cell that includes a first electrode, a second electrode, and a photoactive layer disposed between the first and second electrodes. The photoactive layer includes a photoactive polymer containing a first monomer repeat unit, which contains a moiety of formula (1): in which A and R are defined in the specification.

  本公开涉及一种光伏电池，包括第一电极、第二电极和位于第一和第二电极之间的光活性层。光活性层包括一种光活性聚合物，该聚合物包含第一单体重复单元，其中包含式（1）的基团：其中A和R在规范中有定义。