BTQBT(升华提纯) | 135704-54-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻二唑类
• 中文名称: BTQBT(升华提纯)
• 英文名称: bis[1,2,5]thiadiazolo-p-quinobis(1,3-dithiole)
• 英文别名: Btqbt；4,8-bis(1,3-dithiol-2-ylidene)-[1,2,5]thiadiazolo[3,4-f][2,1,3]benzothiadiazole
• CAS: 135704-54-0
• 化学式: C₁₂H₄N₄S₆
• 分子量: 396.587
• InChiKey: ABMLGFPCLXTCEI-UHFFFAOYSA-N

物化性质

• 熔点：
  400°C(lit.)
• 沸点：
  576.2±50.0 °C(Predicted)
• 密度：
  1.927±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  22
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  209
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  2-(1,3-二噻吩)磷酸二甲酯 、 4H,8H-benzo<1,2-c:4,5-c'>bis<1,2,5>thiadiazole-4,8-dione 在 正丁基锂 作用下， 生成 BTQBT(升华提纯)
  参考文献：
  名称：

  Preparation and properties of bis[1,2,5]thiadiazolo-p-quinobis(1,3-dithiole) (BTQBT) and its derivatives. Novel organic semiconductors

  摘要：

  Bis[1,2,5]thiadiazlo-p-quinobis(1,3-dithiole) (BTQBT) (3a) and its derivatives 3b-f were prepared by using a Wittig-Horner reaction. The conductivity of BTQBT was good as a single component. The X-ray structural analysis reveals that the planar molecule forms a sheetlike network by short S---S contacts. The conductivities of the derivatives 3b-f were poorer than that of BTQBT, indicating that the unique crystal structure of BTQBT is needed for the good conductivity. The selenadiazolo analogues 9a,b were also prepared. The conductivities were a little higher than that of BTQBT due to the stronger intermolecular interactions caused by the selenium atom.

  DOI：

  10.1021/jo00046a039

文献信息

• Yamashita, Yoshiro; Tanaka, Shoji; Imaeda, Kenichi, Chemistry Letters, 1991, p. 1213 - 1216
  作者：Yamashita, Yoshiro、Tanaka, Shoji、Imaeda, Kenichi、Inokuchi, Hiroo

  DOI：——

  日期：——
• ORGANIC LIGHT EMITTING ELEMENT
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20160079544A1

  公开（公告）日：2016-03-17

  Provided is an organic light emitting element having stable performance in the air. The organic light emitting element includes: an anode; a cathode; and a first organic compound layer placed between the anode and the cathode, in which: the organic light emitting element further includes a first organic compound layer placed between the cathode and the emission layer, and a second organic compound layer placed between the emission layer and the first organic compound layer, and brought into contact with the first organic compound layer; the first organic compound layer contains a first organic compound; the second organic compound layer contains a second organic compound; and the first organic compound includes an organic compound represented by the following general formula [1], and the second organic compound includes an organic compound different from the first organic compound
• US9818957B2
  申请人：——

  公开号：US9818957B2

  公开（公告）日：2017-11-14