| 1092379-57-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1092379-57-1
• 化学式: C₄₄H₂₈Cl₂N₆Zn
• 分子量: 777.043
• InChiKey: UGOKNPHQEBJVEY-IBSAJEPBSA-N

反应信息

• 作为产物：
  描述：

  邻氯苯胺 、 [5,15-dibromo-10,20-diphenylporphinato]zinc(II) 在 sodium tetrachloroaurate(III) dihyrate 、 碘苯二乙酸 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 以72%的产率得到
  参考文献：
  名称：

  Facile and Efficient Hypervalent Iodine(III)-Mediated meso-Functionalization of Porphyrins

  摘要：

  Highly facile and efficient synthesis of a variety of meso-functionalized porphyrins was accomplished by PhI(OAc)(2)-NaAuCl4 mediated direct nucleophilic substitution reactions of [5,10,1 5-triphenylporphyrinato]zinc(II) (Zn1) with different amines and thiophenols. When [5,15-dibromo-10,20-diphenylporphyrinato]zinc(II) (Zn12) was used as the starting porphyrin under similar conditions, the double nucleophilic substitution products were obtained in good yields.

  DOI：

  10.1021/jo801855d