bis(1,10-phenanthroline)(1,10-phenanthrolino[5,6-b]1,4,5,8,9,12-hexaazatriphenylene)ruthenium(II)(2+) | 186840-34-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: bis(1,10-phenanthroline)(1,10-phenanthrolino[5,6-b]1,4,5,8,9,12-hexaazatriphenylene)ruthenium(II)(2+)
• 英文别名: bis(1,10-phenanthroline)(1,10-phenanthrolino[5,6-b]1,4,5,8,9,12-hexaazatriphenylene)ruthenium(II)；[Ru^II(1,10-phenanthroline)₂(phenanthrolino[5,6-b]1,4,5,8,9,12-hexaazatriphenylene)]²⁺；[Ru^II(phen)₂(PHEHAT)]²⁺；[Ru(II)(1,10-phenanthroline)2(1,10-phenanthrolino[5,6-b]1,4,5,8,9,12-hexaazatriphenylene)](2+)；[(1,10-phenanthroline)2Ru(1,10-phenanthrolino[5,6-b]-1,4,5,8,9,12-hexaazatriphenylene)](2+)；[Ru(1,10-phenanthroline)2(1,10-phenanthrolino[5,6-b]-1,4,5,8,9,12-hexaazatriphenylene)](2+)
• CAS: 186840-34-6；868588-11-8
• 化学式: C₄₆H₂₆N₁₂Ru
• 分子量: 847.863
• InChiKey: UJKLBXVNZKLJFL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 Ru(phen)₂Cl₂ 、 bis(1,10-phenanthroline)(1,10-phenanthrolino[5,6-b]1,4,5,8,9,12-hexaazatriphenylene)ruthenium(II)(2+) 以 乙二醇 为溶剂， 生成 ((phenanthroline)2Ru-μ-(1,10-phenanthrolino[5,6-b]-1,4,5,8,9,12-hexaazatriphenylene)-Ru(phenanthroline)2)(PF6)4
  参考文献：
  名称：

  基于非对称PHEHAT桥接配体及其结构单元的树枝状四核Ru（II）配合物：合成，表征以及电化学和光物理性质。

  摘要：

  基于PHEHAT配体的双核和四核Ru（II）化合物1、2、3和4（PHEHAT = 1,10-菲咯啉[5,6-b] -1,4,5,8,9,12-六氮杂三苯并）是根据其他相关单核物种的数据制备和表征的。讨论了它们的电化学和光谱行为。在这些数据的基础上解释了针对1、2、3和4所获得的非光谱电化学相关性。从发射行为可以得出结论，内部能量在3和4中从铁心传递到外围金属单元。

  DOI：

  10.1021/ic048941q

文献信息

• Dinuclear Ru^IIPHEHAT and -TPAC Complexes:  Effects of the Second Ru^II Center on Their Spectroelectrochemical Properties
  作者：Benjamin Elias、Leslie Herman、Cécile Moucheron、Andrée Kirsch-De Mesmaeker

  DOI：10.1021/ic070224j

  日期：2007.6.1

  Four novel dinuclear Ru-II compounds and, for comparison purposes, two corresponding mononuclear complexes containing the PHEHAT or TPAC ligand (PHEHAT = 1,10-phenanthrolino[5,6-b]-1,4,5,8,9,12-hexaazatriphenylene and TPAC = tetrapyrido[3,2-a:2',3'-c:3" ,2"-h:2''',3'''-j]acridine) have been synthesized and characterized. Conclusions on the effects of dinucleation of these two bridging ligands can be drawn only for the compounds for which the results demonstrate that the bridging ligand is involved in the first electrochemical reduction and lowest emission energy. The behavior of these complexes, which is not always predictable, is discussed, and the differences are highlighted in this work. Interestingly, all of the compounds are luminescent except one dinuclear species, [(phen)(2)Ru-mu-PHEHAT-Ru(TAP)(2)](4+), which does not luminesce in MeCN and BuCN at room temperature.