[La(1,10-phenanthroline)3(2,4,5-trichlorophenylcyanamide(-H))3] | 1358945-19-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: [La(1,10-phenanthroline)3(2,4,5-trichlorophenylcyanamide(-H))3]
• 英文别名: [La(phen)3(2,4,5-Cl3pcyd)3]
• CAS: 1358945-19-3
• 化学式: C₅₇H₃₀Cl₉LaN₁₂
• 分子量: 1340.93
• InChiKey: LGUZVACFKNDIRU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  thallium (2,4,5-trichlorophenyl)cyanamide 、 [La(1,10-phenanthroline)3Cl3]*H2O 以 水 为溶剂， 以80%的产率得到[La(1,10-phenanthroline)3(2,4,5-trichlorophenylcyanamide(-H))3]
  参考文献：
  名称：

  Lanthanum(III) complexes with phenylcyanamide ligands: Synthesis and crystal structure

  摘要：

  Several novel mixed ligand lanthanum complexes with 1,10-phenantroline and phenylcyanamide derivatives with the formula of [La(phen)3Cl(3)center dot OH2] (1) and [La(phen)(3)L-3] (phen = 1,10-phenantroline; L = 2-clorophenylcyanamide (2), 2,5-dichlorophenylcyanamide (3), 2,4-dichlorophenycyanamide (4) and 2,4,5-trichorophenycyanamide (5)) are successfully synthesized in aqueous solution. The complexes are characterized by spectroscopic analysis such as infrared, H-1 NMR, UV-Vis spectroscopy as well as elemental analysis. The molecular structure of 3 is determined by single-crystal X-ray diffraction method. Three 2,5-Cl(2)pcyd and three phenanthroline ligands are coordinated to the central La atom in monodentate and bidentate manner, respectively. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.10.050