[La(1,10-phenanthroline)3Cl3]*H2O | 1358945-13-7

• 英文名称: [La(1,10-phenanthroline)3Cl3]*H2O
• 英文别名: [La(phen)3Cl3]*H2O
• CAS: 1358945-13-7
• 化学式: C₃₆H₂₄Cl₃LaN₆*H₂O
• 分子量: 803.907
• InChiKey: AARDOMWRFVBRSJ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  thallium (2,4-dichlorophenyl)cyanamide 、 [La(1,10-phenanthroline)3Cl3]*H2O 以 水 为溶剂， 以84%的产率得到[La(1,10-phenanthroline)3(2,4-dichlorophenylcyanamide(-H))3]
  参考文献：
  名称：

  Lanthanum(III) complexes with phenylcyanamide ligands: Synthesis and crystal structure

  摘要：

  Several novel mixed ligand lanthanum complexes with 1,10-phenantroline and phenylcyanamide derivatives with the formula of [La(phen)3Cl(3)center dot OH2] (1) and [La(phen)(3)L-3] (phen = 1,10-phenantroline; L = 2-clorophenylcyanamide (2), 2,5-dichlorophenylcyanamide (3), 2,4-dichlorophenycyanamide (4) and 2,4,5-trichorophenycyanamide (5)) are successfully synthesized in aqueous solution. The complexes are characterized by spectroscopic analysis such as infrared, H-1 NMR, UV-Vis spectroscopy as well as elemental analysis. The molecular structure of 3 is determined by single-crystal X-ray diffraction method. Three 2,5-Cl(2)pcyd and three phenanthroline ligands are coordinated to the central La atom in monodentate and bidentate manner, respectively. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.10.050
• 作为产物：
  描述：

  1,10-菲罗啉 、 氯化镧水合物 、 水 以 乙醇 为溶剂， 以88%的产率得到[La(1,10-phenanthroline)3Cl3]*H2O
  参考文献：
  名称：

  Lanthanum(III) complexes with phenylcyanamide ligands: Synthesis and crystal structure

  摘要：

  Several novel mixed ligand lanthanum complexes with 1,10-phenantroline and phenylcyanamide derivatives with the formula of [La(phen)3Cl(3)center dot OH2] (1) and [La(phen)(3)L-3] (phen = 1,10-phenantroline; L = 2-clorophenylcyanamide (2), 2,5-dichlorophenylcyanamide (3), 2,4-dichlorophenycyanamide (4) and 2,4,5-trichorophenycyanamide (5)) are successfully synthesized in aqueous solution. The complexes are characterized by spectroscopic analysis such as infrared, H-1 NMR, UV-Vis spectroscopy as well as elemental analysis. The molecular structure of 3 is determined by single-crystal X-ray diffraction method. Three 2,5-Cl(2)pcyd and three phenanthroline ligands are coordinated to the central La atom in monodentate and bidentate manner, respectively. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.10.050