| 308322-96-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 308322-96-5
• 化学式: C₁₄H₂₈N₂S₂*Ni
• 分子量: 347.212
• InChiKey: WTDMYDWELPLKSL-FXMYHANSSA-L

反应信息

• 作为反应物：
  描述：

  copper(l) iodide 、 以 乙腈 为溶剂， 生成 bis[(1S,2S)-trans-3,3'-(1,2-cyclohexanediyldinitrilo)bis(2-methylpropane-2-thiolato))-1κ(4)N(1),N(1'),S(1),S(1');2κ(4)N(2),N(2'),S(2),S(2');3.kappa(2)S(1),S(2');4κ(2)S(1'),S(2);5κ(2)S(1'),S(2')-triiodo-3κI,4κI,
  参考文献：
  名称：

  A Mixed-Metal Pentanuclear Complex Containing Linked NiIIN2S2 and CuII Units

  摘要：

  Bis[(1S,2S)-trans-3,3'-(1,2-cyclohexanediyldinitrilo)bis(2-methylpropane-2-thiolato)]-1 kappa(4)N(1),N-1',S-1,S-1';2 kappa(4)N(2),N-2',S-2,S-2';3 kappa(2)S(1),S-2';4 kappa(2)S(1'),S-2;5 kappa(2)S(1'),S-2'-tribis(acetonitrile solvate, [{Ni(C14H28N2S2)}(2)(CuI)(3)].2CH(3)CN, is ne of a number of possible novel pentanuclear complexes formed from M(II)N(2)S(2) units with available donating thiolate ligands. In the title conmpound, three (CuI)-I-I groups bridge thiolate ligands from two approximately square-planar [(NiN)-N-II(amine)(2)S(thiolate)(2)] units to form the pentanuclear complex. The coordination geometry of each Cu atom is approximately trigonal planar.

  DOI：

  10.1107/s0108270196001308