[-(NC)5Fe(II)-CN-Pt(IV)(NH3)4-]n | 166264-21-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [-(NC)5Fe(II)-CN-Pt(IV)(NH3)4-]n
• CAS: 166264-21-7
• 化学式: C₆H₁₂FeN₁₀Pt
• 分子量: 475.155
• InChiKey: QDUKVGBZIFBMTI-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  以 水 为溶剂， 生成 [-(NC)5Fe(II)-CN-Pt(IV)(NH3)4-]n
  参考文献：
  名称：

  Development of Redox-Active Optical Mesostructures at Chemically Modified Electrode Interfaces

  摘要：

  Polymeric films of [Fe-II(CN)(6)-Pt-IV(NH3)(4)](n) were prepared on optically transparent indium tin oxide (ITO) electrode surfaces via oxidative polymerization of the monomer [Pt(NH3)(4)](2)[(NC)(5)Fe-CN-Pt(NH3)(4)-NC-Fe(CN)(5)]. Irradiation at 457 nm into the intervalence charge transfer band of the interfacial polymer causes the cleavage of bridging -CN- to Pt bonds, leading to the dissociation of polymeric film into shorter-chain [Fe-Pt](n) oligomers, [Pt(NH3)(4)](2+) and [Fe(CN)(6)](3-). When photolysis is carried out with the modified interface immersed in an aqueous solution containing transition metal cations M(n+) (M(n+) = Ni2+, Fe2+, Mn2+, Cr3+), M(n+) reacts with photogenerated [Fe(CN)(6)](3-) complexes to form mixed metal cyanometalates of the form [M-NC-Fe(CN)(5)](2-) on the electrode surface. As a result, M(n+) is incorporated into the interfacial lattice only at the irradiated regions. The film after M(n+) incorporation is different in color compared to the original [Fe-Pt](n) polymer film. Images may be developed on such a film by irradiating the sample through a mask. In this paper we report: the formation and characterization of such multicomponent electrode surfaces. In addition, the potential applicability of these multicomponent electrodes as molecular electronic devices is discussed.

  DOI：

  10.1021/ic00120a036

文献信息

• Chang, Clark; Ludwig, David; Bocarsly, Andrew, Inorganic Chemistry, <hi>1998</hi>, vol. 37, # 21, p. 5467 - 5473
  作者：Chang, Clark、Ludwig, David、Bocarsly, Andrew

  DOI：——

  日期：——