| 149492-39-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• CAS: 149492-39-7
• 化学式: C₁₄H₁₇ClN₂O₂
• 分子量: 280.754
• InChiKey: JOQHVKJTNMZOLM-UHFFFAOYSA-N

物化性质

• 沸点：
  459.2±45.0 °C(predicted)
• 密度：
  1.16±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

反应信息

• 作为反应物：
  描述：

  manganese(II) perchlorate hexahydrate 、 在 NaOH 作用下， 以 甲醇 、 乙醇 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Synthesis and characterisation of manganese(III) unsymmetrical Schiff-base complexes: a unique example of a cocrystallised manganese(III) unsymmetrical Schiff-base complex, and a symmetric Schiff-base complex arising from rearrangement of the former

  摘要：

  Some manganese(III) complexes with unsymmetrical Schiff bases have been prepared and characterised. The ligands were prepared by condensation of 7-amino-4-methyl-5-azahept-3-en-2-one with salicylaldehyde, 2-hydroxyacetophenone or substituted salicylaldehydes (5-chloro, 5-methoxy, 3-ethoxy or 3,5-dibromo). On reaction with manganese(II) perchlorate in air, manganese(III) Schiff-base complexes are obtained. The crystal structures of two of these have been determined, one being cocrystallised with [{Mn(salen)(H2O)}2][ClO4]2 containing the symmetrical salen ligand [N,N'-ethane-1,2-diylbis(salicylideneiminate)]. Unlike the dimeric structures previously found for similar complexes, the two structures are monomeric with octahedral MnN2O4 co-ordination spheres.

  DOI：

  10.1039/dt9930001605

文献信息

• Synthesis and characterization of vanadyl complexes with unsymmetrical bis-schiff base ligands containing a cis-N2O2 coordinate chromophore1
  作者：Xiu R. Bu、Eric A. Mintz、Xiao Z. You、Rei X. Wang、Yue Qi、Qin J. Meng、Yun J. Lu、Donald Van Derveer

  DOI：10.1016/0277-5387(96)00220-3

  日期：1996.9

  Abstract Eight new vanadyl complexes utilizing unsymmetrical bis-Schiff base ligands [VOL, H 2 L = o -HOArC(R)NCH 2 CH 2 NHC(CH) 3 )CHC(O)CH 3 ], prepared from ethylene-diamine, acetylacetone and a salicylaldehyde derivative have been synthesized and characterized. A 0 and g 0 values determined by ESR were found to be solvent-independent. Substituents on the phenyl ring of the ligand strongly effect

  摘要由乙烯制备的八种利用不对称双席夫碱配体[VOL，H 2 L = o-HOArC（R）NCH2 CH 2 NHC（CH）3）CHC（O）CH 3]的新的钒基配合物-二胺，乙酰丙酮和水杨醛衍生物已经合成并表征。发现通过ESR确定的0和g 0值与溶剂无关。配体的苯环上的取代基强烈影响A 0，强烈吸电子基团产生更高的A 0值，但是g 0仅受到环取代基的轻微影响。VO [2-O-3,5-Br 2 C 6 H 2 C（CH 3）NCH2 CH 2 NC（CH 3）CHC（O）CH 3（VOL 8）的特征在于单晶X-射线晶体学分析，发现钒在基面上方位移了0.612A。