zinc(II) 3,3',3'',3'''-tetramethoxyphenylimino phthalocyanine | 1131600-08-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: zinc(II) 3,3',3'',3'''-tetramethoxyphenylimino phthalocyanine
• CAS: 1131600-08-2
• 化学式: C₆₄H₄₄N₁₂O₄Zn
• 分子量: 1110.52
• InChiKey: DHGQQLSCGCFOKQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  zinc(II) 3,3',3'',3'''-tetramethoxyphenylimino phthalocyanine 以 neat (no solvent) 为溶剂， 生成 zinc(II) oxide
  参考文献：
  名称：

  Synthesis, structural investigations and biological studies on symmetrically substituted 3,3′,3",3"′-tetra-methoxyphenylimino phthalocyanine complexes

  摘要：

  The present paper describes the synthesis and characterization of novel metal (II) 3,3',3aEuro(3),3aEuro '-tetramethoxyphenylimino substituted phthalocyanines (M-MeOPhImPcs) of copper (II), cobalt (II), nickel (II) and zinc (II) by condensing the 3,3',3aEuro(3),3aEuro(3)aEuro(2)-tetra amino phthalocyanines with anisaldehyde. The dark bluish green colored tetraimino substituted phthalocyanine derivatives were characterized by various physico-chemical techniques like elemental analysis, magnetic susceptibility, electronic, IR, powder X-ray diffraction and thermo gravimetric analysis (TGA) to check the structural integrity and purity. The variations of magnetic moment as a function of field strength indicated the presence of inter molecular co-operative interactions. The complexes were also evaluated for their antifungal and antibacterial activities.

  DOI：

  10.1134/s0036023608010117
• 作为产物：
  描述：

  1,8,15,22-tetraamino zinc phthalocyanine 、 邻甲氧基苯甲醛 在 H₂SO₄ 作用下， 以 二甲基亚砜 为溶剂， 以82%的产率得到zinc(II) 3,3',3'',3'''-tetramethoxyphenylimino phthalocyanine
  参考文献：
  名称：

  Synthesis, structural investigations and biological studies on symmetrically substituted 3,3′,3",3"′-tetra-methoxyphenylimino phthalocyanine complexes

  摘要：

  The present paper describes the synthesis and characterization of novel metal (II) 3,3',3aEuro(3),3aEuro '-tetramethoxyphenylimino substituted phthalocyanines (M-MeOPhImPcs) of copper (II), cobalt (II), nickel (II) and zinc (II) by condensing the 3,3',3aEuro(3),3aEuro(3)aEuro(2)-tetra amino phthalocyanines with anisaldehyde. The dark bluish green colored tetraimino substituted phthalocyanine derivatives were characterized by various physico-chemical techniques like elemental analysis, magnetic susceptibility, electronic, IR, powder X-ray diffraction and thermo gravimetric analysis (TGA) to check the structural integrity and purity. The variations of magnetic moment as a function of field strength indicated the presence of inter molecular co-operative interactions. The complexes were also evaluated for their antifungal and antibacterial activities.

  DOI：

  10.1134/s0036023608010117