[bis(quinoline)-μ-(1,1-dioxide-1,2-benzoisothiazol-3-thionato-κ(1)S,κ(3)N)-μ-(1,1-dioxide-1,2-benzoisothiazol-3-3-thionato-κ(1)N,κ(3)S)-disilver(I)] | 1222172-15-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: [bis(quinoline)-μ-(1,1-dioxide-1,2-benzoisothiazol-3-thionato-κ(1)S,κ(3)N)-μ-(1,1-dioxide-1,2-benzoisothiazol-3-3-thionato-κ(1)N,κ(3)S)-disilver(I)]
• CAS: 1222172-15-7
• 化学式: C₃₂H₂₂Ag₂N₄O₄S₄
• 分子量: 870.551
• InChiKey: PCXAMFCSXGAWGZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  喹啉 、 (silver)6(thiosaccharinate)6 以 喹啉 为溶剂， 以72%的产率得到[bis(quinoline)-μ-(1,1-dioxide-1,2-benzoisothiazol-3-thionato-κ(1)S,κ(3)N)-μ-(1,1-dioxide-1,2-benzoisothiazol-3-3-thionato-κ(1)N,κ(3)S)-disilver(I)]
  参考文献：
  名称：

  Different coordination modes of the thiosaccharinate anion in dinuclear and one dimensional polymeric silver–azine complexes

  摘要：

  The effect of substituted pyridines bases upon the coordination of thiosaccharinate (tsac, C(7)H(4)NO(2)S(2)(-) in ternary silver complexes is analyzed. Four crystalline silver-substituted pyridine complexes with tsac as a coordinating counter anion, [Ag(tsac)(3-methylpyridine)(2)](n), [Ag(2)(tsac)(2)(4-methylpyridine)](n), [Ag(2)(tsac)(2)(quinoline)(2)] and [Ag(tsac)(4-methyloxypyridine)](n) were synthesized and characterized by means of spectroscopic (IR and Raman, UV-Vis, and (1)H and (13)C NMR) and X-ray diffraction techniques. The thiosaccharinate anion showed its versatility coordinating to the metal in each complex by a different way. In the 3-Mepy complex it was coordinated in a mu(2)-S mode and in the 4-MeOpy complex it was bound in a mu(3)-S form both resulting in polymeric chains. In the 4-Mepy complex the anion was bound in a mu(2)-S,N head to head mode and in the quinoline complex in a mu(2)-S,N head to tail mode, both showing dinuclear arrangements. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.12.025