1-chlorobutane radical | 65161-22-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 1-chlorobutane radical
• CAS: 65161-22-0
• 化学式: C₄H₈Cl
• 分子量: 91.5605
• InChiKey: UEJMVDDOHPPQJJ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  氯丁烷 以 水 为溶剂， 生成 1-chlorobutane radical
  参考文献：
  名称：

  Fast hydrolysis of alkyl radicals with leaving groups in the β position

  摘要：

  DOI：

  10.1021/ja00389a068

文献信息

• Kinetic study of OH radical reactions with chlorobutane isomers at 298K
  作者：J.C. Loison、L. Ley、R. Lesclaux

  DOI：10.1016/s0009-2614(98)01058-6

  日期：1998.11

  The rate constant of hydroxyl radical reactions with the four chlorobutane isomers have been determined using a fast flow reactor. The values in cm(3) molecule(-1) s(-1) are: k(1) (OH + 1-chlorobutane) = (2.00 +/- 0.15) x 10(-12), k(2) (OH + 2-chlorobutane) = (2.45 +/- 0.30) x 10(-12), k(3) (OH + 1-chloro-2-methylpropane) = (1.95 +/- 0.20) x 10(-12), k(4) (OH + 2-chloro-2-methylpropane)= (0.45 +/- 0.10) x 10(-12). The quoted errors include both statistical deviations (2 sigma generally < 5%) and estimated systematic uncertainties (10-20%). Adjustments of structure activity relationships are suggested. (C) 1998 Elsevier Science B.V. All rights reserved.