| 162288-76-8

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 均质其他非金属化合物
• CAS: 162288-76-8
• 化学式: P₁₄
• 分子量: 433.633
• InChiKey: IDQOYRKWZVRIMN-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  在 (n)Bu₃SnCl 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Facile Interconversion of Polyphosphides and Formation of a New Polyphosphide Anion

  摘要：

  The last 2 decades have seen the synthesis of a variety of polynuclear phosphorus compounds with phosphorus-phosphorus-bonded skeletal arrangements. However, many synthetic aspects of these compounds have remained unclear. The effect of solvent on the relative stability of the hexadecaphosphide dianion (P-16(2-)) and the henicosaphosphide trianion (P-21(3-)) is established in this account, thus demonstrating the first redox interconversion of two homopolyatomic phosphorus anions.

  DOI：

  10.1021/ic00115a002