[Co(2-((2-pyridylethyl)imino)-3-butanone oximato)2]ClO4 | 86561-23-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯并吡啶类
• 英文名称: [Co(2-((2-pyridylethyl)imino)-3-butanone oximato)2]ClO4
• CAS: 86561-23-1
• 化学式: C₂₂H₂₈CoN₆O₂*ClO₄
• 分子量: 566.947
• InChiKey: VUSSROHGHNPIAC-RTSMVXIYSA-K

反应信息

• 作为反应物：
  描述：

  [Co(2-((2-pyridylethyl)imino)-3-butanone oximato)2]ClO4 、 氯化苄 在 NaBH₄ 、 NaOH 作用下， 以 甲醇 、 水 为溶剂， 生成 [C6H5CH2Co(2-((2-pyridylethyl)imino)-3-butanone oximato)(2-((2-pyrodylethyl)amino)-3-aminobutane)]ClO4
  参考文献：
  名称：

  Synthesis, Characterization, and Reactivity of a New Mononuclear Benzyl−Cobalt Complex Containing Mixed Tridentate Imino−Oxime and Diamine Ligands

  摘要：

  The complex [C6H5CH2Co(L)(LR)]ClO4 (3), where L = 2-((2-pyridylethyl)imino)-3-butanone oximato and LR = 2-((2-pyridylethyl)amino)-3-aminobutane has been prepared by reduction, with NaBH4 of the complex [Co-III(L)(2)]ClO4, followed by addition of C6H5CH2Cl. The compounds was characterized in the solid state by X-ray analysis. The complex undergoes Co-C homolytic cleavage under acidic conditions, giving dibenzyl under a nitrogen atmosphere and benzaldehyde in the presence of air.

  DOI：

  10.1021/om970967k