4-Acetoxyphenethyl acrylate | 926305-16-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 4-Acetoxyphenethyl acrylate
• 英文别名: 2-(4-acetyloxyphenyl)ethyl prop-2-enoate
• CAS: 926305-16-0
• 化学式: C₁₃H₁₄O₄
• 分子量: 234.25
• InChiKey: UPRJCBCFGSJZJU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  17
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• WGK Germany：
  3

文献信息

• [EN] FORCE-RESPONSIVE POLYMERSOMES AND NANOREACTORS; PROCESSES UTILIZING THE SAME<br/>[FR] POLYMERSOMES ET NANORÉACTEURS SENSIBLES À LA FORCE; PROCÉDÉS LES UTILISANT
  申请人：ADOLPHE MERKLE INSTITUTE UNIV OF FRIBOURG

  公开号：WO2019034597A1

  公开（公告）日：2019-02-21

  The mechanically induced melting properties of DNA were employed to achieve force labile membranes is described. Nucleobase pairs were used as mechanophores. Adenine and thymine functionalized complementary amphiphilic block copolymers were self-assembled into polymersomes. The nucleobases formed hydrogen bonds which were disrupted upon force stimulation. The exposure of the disconnected nucleobases to the hydrophobic matrix of the membranes lead to a change of permeability which permitted the exchange of water-soluble molecules throughout the polymer matrix. Moreover, the encapsulation of horseradish peroxidase enabled the reaction of luminol with hydrogen peroxide to yield a luminescence producing species similar to the marine bioluminescence. Moreover, the same nano-reactors were employed to catalyze the formation of a polyacrylamide gel when force was applied. Insights into the change of permeability of supramolecular networks upon force are provided. These systems are useful for drug delivery, as nanoreactors and for the selective release of curing agents for 3D printing, or fragrances.

  DNA的机械诱导熔化特性被用来实现易受力破裂的膜。核碱基对被用作机械感受器。腺嘌呤和胸腺嘧啶功能化的互补两性分块共聚物自组装成聚合体囊。核碱基形成氢键，在受力刺激下被破坏。断开的核碱基暴露在膜的疏水基质中，导致渗透性的改变，从而允许水溶性分子在聚合物基质中交换。此外，封装辣根过氧化物酶使得辣根酰胺与过氧化氢反应产生类似海洋生物发光的发光物种。此外，当施加力时，相同的纳米反应器被用来催化聚丙烯酰胺凝胶的形成。提供了关于受力下超分子网络渗透性变化的见解。这些系统可用于药物传递、纳米反应器以及用于3D打印的固化剂或香料的选择性释放。
• CURATIVES FOR EPOXY ADHESIVE COMPOSITIONS
  申请人：Dershem Stephen M.

  公开号：US20100113643A1

  公开（公告）日：2010-05-06

  The invention provides epoxy and oxetane compositions including the novel acyloxy and N-acyl curing agents described herein. Use of invention curing agents result in cured adhesive compositions with remarkably increased adhesion and reduced hydrophilicity when compared to resins cured with other types of curing agents. Furthermore, the curatives of this invention do not interfere with free-radical cure and are thus suited for use in hybrid cure thermoset compositions.

  该发明提供了包括新型酰氧基和N-酰基固化剂的环氧树脂和氧环烷组合物。使用该发明的固化剂可使胶粘剂组合物固化后的粘附性大大增加，并且与用其他类型的固化剂固化的树脂相比，其亲水性减少。此外，该发明的固化剂不会干扰自由基固化，因此适用于混合固化热固性组合物的使用。
• SOLID-SUPPORTED PALLADIUM(II) COMPLEX FOR CATALYZING MIZOROKI-HECK COUPLING REACTIONS AND A METHOD THEREOF
  申请人：KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

  公开号：US20180065117A1

  公开（公告）日：2018-03-08

  A solid-supported palladium(II) complex which catalyzes the Mizoroki-Heck coupling reaction efficiently and a method of employing the solid-supported palladium(II) complex to synthesize cinnamic acid and derivatives thereof. The solid-supported palladium(II) complex is also stable and can be recycled without significantly losing catalytic activity.

  一种固体支持的钯(II)配合物能高效催化Mizoroki-Heck偶联反应，并且使用这种固体支持的钯(II)配合物合成肉桂酸及其衍生物的方法。这种固体支持的钯(II)配合物也稳定，并且可以循环利用而且不会显著丧失催化活性。
• LOW VISCOSITY, LOW VOLATILITY LUBRICATING OIL BASESTOCKS
  申请人：Patil Abhimanyu O.

  公开号：US20150275127A1

  公开（公告）日：2015-10-01

  This disclosure provides low viscosity, low volatility alkylated siloxane compounds and alkylated alkoxy silane compounds. This disclosure also provides processes for producing the alkylated siloxane compounds and alkylated alkoxy silane compounds, and lubricating oil basestocks and lubricating oils containing one or more of the alkylated siloxane compounds or one or more of the alkylated alkoxy silane compounds. This disclosure further provides a method for improving one or more of solubility and dispersancy of polar additives and/or sludge in a lubricating oil by using as the lubricating oil a formulated oil containing one or more of the alkylated siloxane compounds or one or more of the alkylated alkoxy silane compounds.

  本公开提供低粘度、低挥发性的烷基化硅氧烷化合物和烷基化烷氧硅烷化合物。本公开还提供生产烷基化硅氧烷化合物和烷基化烷氧硅烷化合物的方法，以及含有一种或多种烷基化硅氧烷化合物或一种或多种烷基化烷氧硅烷化合物的润滑油基础油和润滑油。本公开进一步提供一种通过使用含有一种或多种烷基化硅氧烷化合物或一种或多种烷基化烷氧硅烷化合物的配方油作为润滑油，来改善极性添加剂和/或沉淀物在润滑油中的溶解性和分散性的方法。
• CURATIVES FOR EPOXY COMPOSITIONS
  申请人：Dershem Stephen M.

  公开号：US20100249276A1

  公开（公告）日：2010-09-30

  The invention provides epoxy and oxetane compositions including the novel acyloxy and N-acyl curing agents described herein. Use of invention curing agents result in cured adhesive compositions with remarkably increased adhesion and reduced hydrophilicity when compared to resins cured with other types of curing agents. Furthermore, the curatives of this invention do not interfere with free-radical cure and are thus suited for use in hybrid cure thermoset compositions.

  本发明提供了环氧和氧杂环烷组分，包括本文所述的新型酰氧基和N-酰基固化剂。使用本发明的固化剂可使固化的粘合剂组分具有显著增强的粘附性和降低的亲水性，与使用其他类型固化剂固化的树脂相比。此外，本发明的固化剂不干扰自由基固化，因此适用于混合固化热固性组分的使用。