| 106287-07-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• CAS: 106287-07-4
• 化学式: C₂₄H₂₈CoN₅O₄
• 分子量: 509.511
• InChiKey: MNHQRFNHXQIJJN-NMBSQECASA-L

反应信息

• 作为产物：
  描述：

  2-溴甲基萘 、 [Co(diphenylglyoximato)₂Cl(pyridine)] 、 trans-bis(dimethylglyoximato)(pyridine)chlorocobalt(III) 在 NaOH 、 NaBH₄ 作用下， 以 甲醇 、 水 为溶剂， 以11%的产率得到[Co(pyridine)(2-naphthyl-CH2)(dimethylglyoximato)(diphenylglyoximato)]
  参考文献：
  名称：

  Organocobaloximes with mixed dioxime equatorial ligands: a convenient one-pot synthesis. X-ray crystal structures of BnCoIII(dmgH)(dpgH)Py and BnCOIII(chgH)(dpgH)py

  摘要：

  A simple and general route to the synthesis of organocobaloxime with mixed dioxime ligands, RCo(dmgH)(dpgH)Py and RCo(chgH)(dpgH)Py, has been described. The C-13-NMR chemical shifts have been analysed to see whether one dioxime wing has any effect on the other dioxime wing. The first crystal structure of an organocobaloxime with mixed dioxime ligand in the same complex, BnCo(dmgH)(dpgH)Py and BnCo(chgH)(dpgH)Py, is reported. (C) 2001 Published by Elsevier Science B.V.

  DOI：

  10.1016/s0022-328x(01)00731-8