(24S)-12α,16β,24-trihydroxy-9,19-cyclolanostan-3β-yl β-D-glucopyranoside | 1260512-86-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 类固醇和类固醇衍生物
• 英文名称: (24S)-12α,16β,24-trihydroxy-9,19-cyclolanostan-3β-yl β-D-glucopyranoside
• 英文别名: (2R,3R,4S,5S,6R)-2-[[(1R,3R,6S,8R,11S,12S,14S,15R,16R,17S)-14,17-dihydroxy-15-[(2R,5S)-5-hydroxy-6-methylheptan-2-yl]-7,7,12,16-tetramethyl-6-pentacyclo[9.7.0.01,3.03,8.012,16]octadecanyl]oxy]-6-(hydroxymethyl)oxane-3,4,5-triol
• CAS: 1260512-86-4
• 化学式: C₃₆H₆₂O₉
• 分子量: 638.883
• InChiKey: FLVNLKYUXMNGEM-UWURSDJTSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  45
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  160
• 氢给体数：
  7
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  (24S)-12α,16β,24-trihydroxy-9,19-cyclolanostan-3β-yl β-D-glucopyranoside 在 alpha-L-rhamnosidase 、 水 作用下， 反应 96.0h， 以6.5 mg的产率得到(24S)-9,19-cyclolanostane-3β,12α,16β,24-tetrol
  参考文献：
  名称：

  Cycloartane glycosides from the rhizomes of Curculigo orchioides

  摘要：

  Cycloartane glycosides (1-9) were Isolated from rhizomes of Curculigo orchioides (Hypoxidaceae) and this structures were determined by spectroscopic analysis and a few chemical transformations Cytotoxic activity of glycosides (1-9) and their common aglycone (1a) against HL-60 human promyelocytic leukemia cells was also examined (C) 2010 Elsevier Ltd All lights reserved

  DOI：

  10.1016/j.phytochem.2010.09.005