3-Prop-2-enylnaphthalen-2-ol | 96964-61-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 3-Prop-2-enylnaphthalen-2-ol
• CAS: 96964-61-3
• 化学式: C₁₃H₁₂O
• 分子量: 184.238
• InChiKey: FRBPTVNPCWFJDR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-Prop-2-enylnaphthalen-2-ol 在 氧气 、 copper(l) chloride 作用下， 以 乙腈 为溶剂， 以56%的产率得到3-Allyl-1,2-naphthoquinone
  参考文献：
  名称：

  Annulation reactions leading to naphthalene derivatives. New syntheses of natural 1,2- and 1,4-naphthoquinones

  摘要：

  DOI：

  10.1021/jo00218a022
• 作为产物：
  描述：

  ethyl 4-(benzenesulfonyl)-3-oxo-2-prop-2-enyl-1,4-dihydronaphthalene-2-carboxylate 在 2,6-二甲基吡啶 、 lithium iodide 作用下， 反应 8.0h， 以63%的产率得到3-Prop-2-enylnaphthalen-2-ol
  参考文献：
  名称：

  Annulation reactions leading to naphthalene derivatives. New syntheses of natural 1,2- and 1,4-naphthoquinones

  摘要：

  DOI：

  10.1021/jo00218a022

文献信息

• An efficient solid-phase synthesis of substituted benzofuran using selenium-bound resin
  作者：Yin jun Zhang、Yu guang Wang

  DOI：10.1002/aoc.2840

  日期：2012.5

  A very efficient solid‐phase synthesis of substituted benzofuran using polymer‐supported selenium resin is described. The advantages of the new method are good yields, high purity, straightforward operations, broad range and high diversity of products, lack of odor, and good stability of the resins. The easy work‐up procedure makes the method suitable for building parallel libraries. Copyright © 2012

  描述了一种使用聚合物负载的硒树脂非常有效地固相合成取代苯并呋喃的方法。新方法的优点是产率高，纯度高，操作简单，产品范围广和多样性高，无气味，树脂的稳定性好。简单的后处理程序使该方法适合于构建并行库。版权所有©2012 John Wiley＆Sons，Ltd.
• METHOD FOR PRODUCING CARBINOL-MODIFIED ORGANOSILOXANE
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：EP3819326A1

  公开（公告）日：2021-05-12

  A method for producing a carbinol-modified organosiloxane, which comprises steps (A) to (C), is an efficient production method whereby it becomes possible to reduce the production of a by-product of the reaction for the production of a terminal-carbinol-modified organosiloxane. (A) a step of supplying the following components (a) to (c) to a tubular reactor continuously: (a) an organohydrogensiloxane represented by formula (I) (wherein R1's independently represent a monovalent hydrocarbon group having 1 to 20 carbon atoms; and m represents an integer of 0 to 500); (b) a compound represented by formula (II):         R2-Z-OH (wherein R2 represents a vinyl group or an allyl group; and Z represents a bivalent hydrocarbon group); and (c) a platinum catalyst in an amount of 0.005 ppm by mass or more and less than 1.0 ppm by mass in terms of metal platinum content relative to the total amount of the components (a) to (c); (B) a step of subjecting the components (a) to (c) to a hydrosilylation reaction while allowing these components to pass through the tubular reactor; and (C) a step of removing a reaction product.

  一种生产甲醇改性有机硅氧烷的方法，包括步骤(A)至(C)，是一种高效的生产方法，可以减少生产端甲醇改性有机硅氧烷反应副产物的产生。 (A) 向管式反应器连续供应以下组分（a）至（c）的步骤： (a) 由式(I)表示的有机氢硅氧烷 (其中 R1's 独立地代表具有 1 至 20 个碳原子的单价烃基；m 代表 0 至 500 的整数）； (b) 由式 (II) 代表的化合物： R2-Z-OH (其中 R2 代表乙烯基或烯丙基；Z 代表二价烃基）；以及 (c) 铂催化剂，相对于(a)至(c)组分的总量，其金属铂含量为 0.005 ppm (质量分数) 或以上，但小于 1.0 ppm (质量分数)； (B) 使(a)至(c)组分进行氢硅烷化反应，同时让这些组分通过管式反应器；以及 (C) 去除反应产物的步骤。
• ACTIVE ESTER RESIN AND COMPOSITION AND CURED PRODUCT USING THE SAME
  申请人：DIC Corporation

  公开号：US20200216603A1

  公开（公告）日：2020-07-09

  The present invention aims to provide a means by which a cured product to be obtained has a low dielectric loss tangent and higher heat resistance. Specifically, provided is an active ester resin that is a reaction product of a first aromatic compound having two or more phenolic hydroxy groups, a second aromatic compound having a phenolic hydroxy group, and a third aromatic compound having two or more carboxy groups and/or an acid halide thereof or an esterified compound thereof, in which at least one of the first aromatic compound, the second aromatic compound, and the third aromatic compound and/or the acid halide thereof or the esterified compound thereof has an unsaturated bond-containing substituent.
• CURABLE COMPOSITION AND CURED PRODUCT THEREOF
  申请人：DIC Corporation

  公开号：US20210009804A1

  公开（公告）日：2021-01-14

  A curable composition to be cured to provide a cured product excellent in heat resistance and dielectric properties, a cured product of the curable composition, a printed wiring board, a semiconductor sealing material, and a build-up film using the curable composition. There is provided a curable composition containing an aromatic ester resin (A) and a maleimide compound (B), the aromatic ester resin (A) being an active ester resin that is a reaction product of a first aromatic compound having two or more phenolic hydroxy groups, a second aromatic compound having a phenolic hydroxy group, and a third aromatic compound having two or more carboxy groups and/or an acid halide thereof or an esterified compound thereof, in which at least one of the first aromatic compound, the second aromatic compound, and the third aromatic compound and/or the acid halide thereof or the esterified compound thereof has a polymerizable unsaturated bond-containing substituent.
• [EN] CURABLE COMPOSITION AND CURED PRODUCT OF SAME<br/>[FR] COMPOSITION DURCISSABLE ET SON PRODUIT DURCI<br/>[JA] 硬化性組成物及びその硬化物
  申请人：DAINIPPON INK & CHEMICALS

  公开号：WO2019188330A1

  公开（公告）日：2019-10-03

  硬化物における耐熱性及び誘電特性に優れる硬化性組成物、前記硬化性組成物の硬化物、前記硬化性組成物を用いたプリント配線基板、半導体封止材料、ビルドアップフィルムを提供する。具体的には、２以上のフェノール性水酸基を有する第１の芳香族化合物と、フェノール性水酸基を有する第２の芳香族化合物と、２以上のカルボキシ基を有する第３の芳香族化合物および／またはその酸ハロゲン化物、エステル化物と、の反応生成物である、活性エステル樹脂であって、前記第１の芳香族化合物、前記第２の芳香族化合物、並びに前記第３の芳香族化合物および／またはその酸ハロゲン化物、エステル化物の少なくとも１つが重合性不飽和結合含有置換基を有する、芳香族エステル樹脂（Ａ）と、マレイミド化合物（Ｂ）とを含有する硬化性組成物を提供する。