4-bromo-N,N-bis[2-[2-(2-methoxyethoxy)ethoxy]ethyl]aniline | 1258154-17-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-bromo-N,N-bis[2-[2-(2-methoxyethoxy)ethoxy]ethyl]aniline
• CAS: 1258154-17-4
• 化学式: C₂₀H₃₄BrNO₆
• 分子量: 464.397
• InChiKey: CHQJZROJLWHGQZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  28
• 可旋转键数：
  19
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  58.6
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  2-(methoxymethoxy)-5-(methoxy)benzeneboronic acid 、 4-bromo-N,N-bis[2-[2-(2-methoxyethoxy)ethoxy]ethyl]aniline 在 四(三苯基膦)钯 、 碳酸氢钠 作用下， 以 水 、 甲苯 为溶剂， 反应 24.0h， 生成
  参考文献：
  名称：

  A highly selective naked-eye probe for hypochlorite with the p-methoxyphenol-substituted aniline compound

  摘要：

  A highly selective naked-eye detection of CIO- is successfully established with probe 1 by taking advantage of the oxidation transformation of p-methoxyphenol into benzoquinone with CIO- and the ICT absorption within the electron donor-acceptor compound. The color of the solution of probe 1 was changed, obviously upon addition of CIO- and CIO- with concentration as low as 1.74 mu M can be analyzed in aqueous solution with probe 1. Moreover, the interferences of other anions can be neglected. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.09.041
• 作为产物：
  描述：

  3,6,9-trioxadecyl iodide 、 4-溴苯胺 在 dipotassium hydrogenphosphate 作用下， 以 乙腈 为溶剂， 反应 72.0h， 以35.5%的产率得到4-bromo-N,N-bis[2-[2-(2-methoxyethoxy)ethoxy]ethyl]aniline
  参考文献：
  名称：

  A highly selective naked-eye probe for hypochlorite with the p-methoxyphenol-substituted aniline compound

  摘要：

  A highly selective naked-eye detection of CIO- is successfully established with probe 1 by taking advantage of the oxidation transformation of p-methoxyphenol into benzoquinone with CIO- and the ICT absorption within the electron donor-acceptor compound. The color of the solution of probe 1 was changed, obviously upon addition of CIO- and CIO- with concentration as low as 1.74 mu M can be analyzed in aqueous solution with probe 1. Moreover, the interferences of other anions can be neglected. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.09.041

文献信息

• A highly selective naked-eye probe for hypochlorite with the p-methoxyphenol-substituted aniline compound
  作者：Kai Cui、Deqing Zhang、Guanxin Zhang、Daoben Zhu

  DOI：10.1016/j.tetlet.2010.09.041

  日期：2010.11

  A highly selective naked-eye detection of CIO- is successfully established with probe 1 by taking advantage of the oxidation transformation of p-methoxyphenol into benzoquinone with CIO- and the ICT absorption within the electron donor-acceptor compound. The color of the solution of probe 1 was changed, obviously upon addition of CIO- and CIO- with concentration as low as 1.74 mu M can be analyzed in aqueous solution with probe 1. Moreover, the interferences of other anions can be neglected. (C) 2010 Elsevier Ltd. All rights reserved.