Superomniphobic coatings and methods of preparation
申请人:UT-Battelle, LLC
公开号:US11311907B2
公开(公告)日:2022-04-26
A composition useful for producing a superomniphobic coating on a substrate, the composition comprising a colloidal suspension of a fluorinated siloxane in a non-silicon-containing fluorinated solvent. In some embodiments, the composition further comprises particles of a hydrophobized metal oxide, e.g., silicon oxide, wherein the hydrophobized metal oxide may be fluorinated. In some embodiments, the composition further comprises a non-silicon-containing fluorinated polymer. The invention is also directed to methods for making the above composition. The invention is also directed to methods for using the above-described composition for rendering a substrate superomniphobic. The aforesaid method comprises depositing a liquid coating solution onto a substrate to form a coated substrate, followed by subjecting the coated substrate to a drying step to remove a liquid phase of the liquid coating solution, wherein the liquid coating solution comprises a colloidal suspension of a fluorinated siloxane in a non-silicon-containing fluorinated solvent.
COMPOSITE MOLDED BODY WITH A LAYER OF A COPOLYMER OF TETRAFLUOROETHYLENE AND PERFLUORO(ETHYL VINYL ETHER)
申请人:Du Pont-Mitsui Fluorochemicals Co. Ltd.
公开号:EP3122557A1
公开(公告)日:2017-02-01
COMPOSITE MOLDED BODY OF A COPOLYMER OF TETRAFLUOROETHYLENE AND PERFLUORO(ETHYL VINYL ETHER)
申请人:Dupont Mitsui Fluorochemicals Co., Ltd.
公开号:US20160185995A1
公开(公告)日:2016-06-30
A composite molded body, and its manufacturing method, is provided wherein the composite body contains a layer comprising a copolymer of tetrafluoroethylene (TFE) and perfluoro(ethyl vinyl ether) (PEVE). The composite body can be manufactured under conditions in which an adjoined layer of thermoplastic resin and/or thermosetting resin is not be melted, thermally degraded or decomposed. The copolymer has a PEVE content of 20 to 80 weight percent, based on the total weight of the copolymer, and a melt flow rate of from 0.1 to 100 g/10 min, as measured in compliance with ASTM D1238 at a temperature of 250° C.±0.1 using a 5 kg weight.
SUPEROMNIPHOBIC COATINGS AND METHODS OF PREPARATION
申请人:UT-Battelle, LLC
公开号:US20190193115A1
公开(公告)日:2019-06-27
A composition useful for producing a superomniphobic coating on a substrate, the composition comprising a colloidal suspension of a fluorinated siloxane in a non-silicon-containing fluorinated solvent. In some embodiments, the composition further comprises particles of a hydrophobized metal oxide, e.g., silicon oxide, wherein the hydrophobized metal oxide may be fluorinated. In some embodiments, the composition further comprises a non-silicon-containing fluorinated polymer. The invention is also directed to methods for making the above composition. The invention is also directed to methods for using the above-described composition for rendering a substrate superomniphobic. The aforesaid method comprises depositing a liquid coating solution onto a substrate to form a coated substrate, followed by subjecting the coated substrate to a drying step to remove a liquid phase of the liquid coating solution, wherein the liquid coating solution comprises a colloidal suspension of a fluorinated siloxane in a non-silicon-containing fluorinated solvent.
HOLLOW FINE PARTICLE PRODUCTION METHOD AND HOLLOW FINE PARTICLES
申请人:DAIKIN INDUSTRIES, LTD.
公开号:US20220056178A1
公开(公告)日:2022-02-24
A method for producing hollow fine particles containing a fluorine-containing resin and having a large average particle size. The method includes a step A of providing hollow fine particles by dispersing a solution containing a fluorine-containing monomer, an oil-soluble initiator, and a non-polymerizable solvent in water containing a fluorine-containing surfactant and thereby polymerizing the fluorine-containing monomer. Also disclosed are hollow fine particles including a fluorine-containing resin and having an average particle size of 70 nm or greater and 10 μm or smaller. The hollow fine particles each have a porosity of 5% by volume or higher, and the fluorine-containing resin contains a polymerized unit based on a fluorine-containing monomer and a polymerized unit based on a crosslinkable monomer.