Ni(4-(trans-2-(5,10,15,20-tetraphenylporphinato-2-yl)ethen-1-yl)benzaldehyde) | 163779-24-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: Ni(4-(trans-2-(5,10,15,20-tetraphenylporphinato-2-yl)ethen-1-yl)benzaldehyde)
• CAS: 163779-24-6
• 化学式: C₅₃H₃₄N₄NiO
• 分子量: 801.569
• InChiKey: RNIUOKAWFHKHOP-BYQIUTHBSA-M

反应信息

• 作为产物：
  描述：

  4-(trans-2'-(5'',10'',15'',20''-tetraphenylporphyrin-2''-yl)ethen-1'-yl)-1-benzaldehyde 、 nickel(II) acetate tetrahydrate 以 甲醇 、 氯仿 、 水 为溶剂， 以71%的产率得到Ni(4-(trans-2-(5,10,15,20-tetraphenylporphinato-2-yl)ethen-1-yl)benzaldehyde)
  参考文献：
  名称：

  Synthesis, Characterization, Structure, Electrochemistry, and Spectroscopy of Porphyrins That Have a Conjugated Connection to Donor/Acceptor Groups

  摘要：

  The reaction of ((tetraphenylporphyrinyl)methyl)triphenylphosphonium chloride and benzaldehydes (CHO-C6H4-R; R = H, NO2, NMe2, OMe, Me, CHO) yields the styryl porphyrin derivatives. These new styryl-substituted porphyrins have been studied using electrochemistry, electronic absorbance, and resonance Raman spectroelectrochemical techniques. The substituents on the styryl group have a modest perturbation on the electronic spectrum of the porphyrin core. The resonance Raman data suggest that a charge-transfer interaction is observed between the porphyrin core and the NO2 group for the 4-NO2 compound.

  DOI：

  10.1021/ic9702330