o-Tolyl-α-naphthylsulfon | 15861-53-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: o-Tolyl-α-naphthylsulfon
• 英文别名: 1-(2-Methylphenyl)sulfonylnaphthalene
• CAS: 15861-53-7
• 化学式: C₁₇H₁₄O₂S
• 分子量: 282.363
• InChiKey: XOONBBMYHOHMQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  42.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  邻甲苯磺酰氯 、 萘 、 三氯化铝 以76%的产率得到
  参考文献：
  名称：

  MURAMOTO YOSHIHIRO; ASAKURA HIDEYUKI; SUSUKI HITOMI, RES. REPTS FAC. ENG. KINKI UNIV.,(1986) N 20, 9-13

  摘要：

  DOI：

文献信息

• Blends of poly (parabanic acids) with other polymers
  申请人：EXXON RESEARCH AND ENGINEERING COMPANY

  公开号：EP0068695A1

  公开（公告）日：1983-01-05

  Homogeneous blends of poly (parabanic acid) resins and aromatic polyether sulfones and terephthalate polyesters are obtained by plasticizing the poly (parabanic acid) resins. The poly (parabanic acid) resins are plasticized with conventional plasticizers for these polymers, such as aromatic polyesters, N,N-dialkyl aromatic sulfonamides, aromatic nitriles, aromatic sulfones and aromatic sulfoxides. Additionally it has been found that polyether sulfones which are free of aliphatic groups are also plasticizers for the poly (parabanic acid) resin.

  通过对聚（对羟基苯甲酸）树脂进行塑化，可获得聚（对羟基苯甲酸）树脂与芳香族聚醚砜和对苯二甲酸酯聚酯的均匀混合物。聚（对苯二甲酸）树脂可使用这些聚合物的常规增塑剂（如芳香族聚酯、N,N-二烷基芳香族磺酰胺、芳香族腈、芳香族砜和芳香族氧化硫）进行增塑。此外，还发现不含脂肪族基团的聚醚砜也是聚对位苯甲酸树脂的增塑剂。
• Polymers containing 1,3-imidazolidine-1,3-diyl rings plasticized with aromatic sulfones or sulfoxides
  申请人：EXXON RESEARCH AND ENGINEERING COMPANY

  公开号：EP0057104A2

  公开（公告）日：1982-08-04

  Normally intractable polymers having the structure: (wherein X is 0 or NH, provided at least one X is 0, R is an organic moiety which may be aliphatic, alicyclic, aromatic or mixtures thereof and n is sufficiently large to give a solid product) such as poly (parabanic acids), are plasticized by composition with an aromatic sulfone or aromatic sulfoxide su such as diphenyl sulfone, diphenyl sulfoxide or dibutyl-4,4'-sulfonyl dibenzoate; levels of from 5 to 60 weight percent of plasticizers are desirable. Such plasticized compositions are useful as magnetic tapes, as films for use in flexible printed circuits, for fibers such as tire cord fibers, for moldings for electrical connectors and coatings for cables, cookware, glass fabrics and industrial belts.

  具有以下结构的通常难以溶解的聚合物： (其中 X 为 0 或 NH，条件是至少有一个 X 为 0，R 为有机分子，可以是脂环族、脂环族、芳香族或其混合物，且 n 足够大以得到固体产品），例如聚（对苯二甲酸），通过与芳香族砜或芳香族亚砜（如二苯基砜、二苯基亚砜或 4,4'-磺酰基二苯甲酸二丁酯）的组合物进行增塑；增塑剂的含量最好在 5 至 60 重量百分比之间。这种增塑组合物可用作磁带、用于柔性印刷电路的薄膜、用于纤维（如轮胎帘子线纤维）、用于电气连接器的模塑以及用于电缆、炊具、玻璃纤维织物和工业皮带的涂层。
• Polymer-metal junction
  申请人：Solvay Specialty Polymers USA, LLC

  公开号：US11359120B2

  公开（公告）日：2022-06-14

  Disclosed is a polymer-metal junction including a polymer composition in contact with a metal substrate, where the polymer composition comprises a polymer component including a PEEK-PEDEK copolymer having a PEEK/PEDEK mole ratio ranging from about 60/40 to about 30/70 and a melting point (Tm) greater than 320° C., and where the polymer composition includes less than 10 wt. % of a sulfur-or-carbonyl-containing solvent, based on the total weight of the polymer composition. Also disclosed are methods of making the polymer-metal junction and articles including the polymer-metal junction.

  本发明公开了一种聚合物-金属接头，包括与金属基板接触的聚合物组合物，其中所述聚合物组合物包含一种聚合物成分，所述聚合物成分包括一种PEEK-PEDEK共聚物，所述PEEK/PEDEK摩尔比范围为约60/40至约30/70，且所述PEEK-PEDEK共聚物的熔点(Tm)大于320°C。此外，所述聚合物组合物中含有一种含硫或羰基的溶剂，其含量小于聚合物组合物总重量的10重量%。本发明还公开了制备所述聚合物-金属接头的方法以及包含所述聚合物-金属接头的产品。
• POLYARYLENE ETHER SULFONE (PAES) COMPOSITIONS
  申请人：Solvay Specialty Polymers USA, LLC.

  公开号：EP2994500A1

  公开（公告）日：2016-03-16
• POLYARYLENE ETHER SULFONE (PAES) POLYMERS
  申请人：Solvay Specialty Polymers USA, L.L.C.

  公开号：EP2994498A2

  公开（公告）日：2016-03-16