[Mn(II)(phenanthroline)2(suberic acid)(1-)]2(suberate)*(suberic acid) | 628286-29-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: [Mn(II)(phenanthroline)2(suberic acid)(1-)]2(suberate)*(suberic acid)
• CAS: 628286-29-3
• 化学式: C₈H₁₄O₄*C₇₂H₇₀Mn₂N₈O₁₂
• 分子量: 1523.47
• InChiKey: AAGXBGDPBZAKKH-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  辛二酸 、 basic manganese carbonate 、 邻菲罗啉 以 甲醇 、 水 为溶剂， 生成 [Mn(II)(phenanthroline)(H2O)3]2*(suberate)*4H2O 、 [Mn(II)(phenanthroline)2(suberic acid)(1-)]2(suberate)*(suberic acid)
  参考文献：
  名称：

  Syntheses and crystal structures of new suberato-bridged Mn(II) phen complexes: {[Mn(phen)2]L2/2}2·H2L·8H2O, {[Mn(phen)(H2O)3]2L}L·2H2L·4H2O and {[Mn(phen)2(HL)]2L}·H2L (H2L=HOOC(CH2)6COOH)

  摘要：

  Three suberato-bridged Mn(II) phen complexes {[Mn(phen)(2)]L-2/2}(2).H2L-8H(2)O (1), {[Mn(phen)(H2O)(3)](2)L}L.2H(2)L.4H(2)O (2) and {[Mn(phen)(2)(HL)](2)L}.H2L (3) have been synthesized and structurally characterized by single crystal X-ray diffraction methods. The [Mn(phen)(2)](2+) moieties in 1 are interlinked by bis-monodentate suberato ligands to generate (1)(infinity)[Mn(phen)(2)L-2/2] polymeric chains. Complex 2 features a nanoporous hydrogen bonded framework made up of suberate anions, suberic acid molecules and lattice water molecules with the bis-monodentate suberato bridged dinuclear {[Mn(phen)(H2O)(3)](2)L}(2+) complex cations residing in tunnels. The bis-monodentate suberato bridged dinuclear {[Mn(phen)(2)(HL)](2)L} molecules in 3 are assembled into a 3D framework with suberic acid molecules situated in the tunnels. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00365-6