[[3,5-Bis[bis(trimethylsilyl)methyl]-2-diethynylsilylphenyl]-trimethylsilylmethyl]-trimethylsilane | 1450630-74-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: [[3,5-Bis[bis(trimethylsilyl)methyl]-2-diethynylsilylphenyl]-trimethylsilylmethyl]-trimethylsilane
• 英文别名: [[3,5-bis[bis(trimethylsilyl)methyl]-2-diethynylsilylphenyl]-trimethylsilylmethyl]-trimethylsilane
• CAS: 1450630-74-6
• 化学式: C₃₁H₆₂Si₇
• 分子量: 631.432
• InChiKey: ULKZBHNKVZUEFR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.98
• 重原子数：
  38
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  [[3,5-Bis[bis(trimethylsilyl)methyl]-2-diethynylsilylphenyl]-trimethylsilylmethyl]-trimethylsilane 在 lithium aluminium tetrahydride 、 正丁基锂 、 四甲基乙二胺 、 三氯硅烷 作用下， 以 四氢呋喃 、 正己烷 、 正庚烷 、 氘代苯 为溶剂， 反应 55.5h， 生成 [[3,5-bis[bis(trimethylsilyl)methyl]-2-(1-phenyl-4H-1,4-phosphasilin-4-yl)phenyl]-trimethylsilylmethyl]-trimethylsilane
  参考文献：
  名称：

  SYNTHESIS OF 1,4-PHOSPHASILACYCLOHEXA-2,5-DIENES BEARING HYDROGEN OR CHLORINE ATOMS ON THE SILICON ATOMS

  摘要：

  2,3,5,6-Unsubstituted 1,4-phosphasilacyclohexa-2,5-dienes bearing a functional group on the silicon atom were synthesized via the corresponding stannacycle. The structures of newly synthesized silacyclic compounds were determined by X-ray crystallographic analysis.

  DOI：

  10.3987/com-12-s(n)114
• 作为产物：
  描述：

  1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene 在 叔丁基锂 作用下， 以 四氢呋喃 为溶剂， 反应 0.5h， 生成 [[3,5-Bis[bis(trimethylsilyl)methyl]-2-diethynylsilylphenyl]-trimethylsilylmethyl]-trimethylsilane
  参考文献：
  名称：

  SYNTHESIS OF 1,4-PHOSPHASILACYCLOHEXA-2,5-DIENES BEARING HYDROGEN OR CHLORINE ATOMS ON THE SILICON ATOMS

  摘要：

  2,3,5,6-Unsubstituted 1,4-phosphasilacyclohexa-2,5-dienes bearing a functional group on the silicon atom were synthesized via the corresponding stannacycle. The structures of newly synthesized silacyclic compounds were determined by X-ray crystallographic analysis.

  DOI：

  10.3987/com-12-s(n)114

文献信息

• SYNTHESIS OF 1,4-PHOSPHASILACYCLOHEXA-2,5-DIENES BEARING HYDROGEN OR CHLORINE ATOMS ON THE SILICON ATOMS
  作者：Norihiro Tokitoh、Yoshiyuki Mizuhata、Satoshi Morikawa

  DOI：10.3987/com-12-s(n)114

  日期：——

  2,3,5,6-Unsubstituted 1,4-phosphasilacyclohexa-2,5-dienes bearing a functional group on the silicon atom were synthesized via the corresponding stannacycle. The structures of newly synthesized silacyclic compounds were determined by X-ray crystallographic analysis.