(E)-N-<1-(1'-naphthyl)ethylidene>-1-phenylethylamine | 100430-66-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (E)-N-<1-(1'-naphthyl)ethylidene>-1-phenylethylamine
• 英文别名: (S)-N-[(1-naphthyl)ethylidene]-1-phenylethylamine；(S,E)-N-(1-(Naphthalen-1-yl)ethylidene)-1-phenylethanamine；1-naphthalen-1-yl-N-[(1S)-1-phenylethyl]ethanimine
• CAS: 100430-66-8
• 化学式: C₂₀H₁₉N
• 分子量: 273.378
• InChiKey: LWYGKPGNUHCTCL-HNNXBMFYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (E)-N-<1-(1'-naphthyl)ethylidene>-1-phenylethylamine 在 palladium on activated charcoal 氢气 作用下， 生成 (1S,1'S)-N-[1'-(1-naphthyl)ethy]-1-phenylethylamine 、 (1S,1'R)-N-[1'-(1-naphthyl)ethy]-1-phenylethylamine
  参考文献：
  名称：

  [PtCl₃(C₂H₄)]^-[AmH]⁺ Complexes Containing Chiral Secondary Amines:  Use as Chiral Derivatizing Agents for the Enantiodiscrimination of Unsaturated Compounds by ¹⁹⁵Pt NMR Spectroscopy and NMR Stereochemical Investigation

  摘要：

  Ionic complexes [PtCl3(C2H4)](-)[AmH](+), containing chiral secondary amines, constitute a versatile class of chiral derivatizing agents (CDAs) for the enantiomeric purity determination of chiral unsaturated compounds via Pt-195 NMR spectroscopy The NMR conformational analysis allows us to search for the stereochemical basis of their enhanced versatility.

  DOI：

  10.1021/jo001165t
• 作为产物：
  描述：

  1-萘乙酮 、 (S)-(-)- α-甲基苄胺 生成 (E)-N-<1-(1'-naphthyl)ethylidene>-1-phenylethylamine
  参考文献：
  名称：

  [PtCl₃(C₂H₄)]^-[AmH]⁺ Complexes Containing Chiral Secondary Amines:  Use as Chiral Derivatizing Agents for the Enantiodiscrimination of Unsaturated Compounds by ¹⁹⁵Pt NMR Spectroscopy and NMR Stereochemical Investigation

  摘要：

  Ionic complexes [PtCl3(C2H4)](-)[AmH](+), containing chiral secondary amines, constitute a versatile class of chiral derivatizing agents (CDAs) for the enantiomeric purity determination of chiral unsaturated compounds via Pt-195 NMR spectroscopy The NMR conformational analysis allows us to search for the stereochemical basis of their enhanced versatility.

  DOI：

  10.1021/jo001165t