4,4,4,3,3,2,2-d₇-butanamide | 1430423-55-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 甲亚胺酸及其衍生物
• 英文名称: 4,4,4,3,3,2,2-d₇-butanamide
• CAS: 1430423-55-4
• 化学式: C₄H₉NO
• 分子量: 94.066
• InChiKey: DNSISZSEWVHGLH-NCKGIQLSSA-N

反应信息

• 作为反应物：
  描述：

  4,4,4,3,3,2,2-d₇-butanamide 在 lithium aluminium deuteride 作用下， 以 乙醚 为溶剂， 反应 12.0h， 以82%的产率得到4,4,4,3,3,2,2,1,1-d₉-butylamine
  参考文献：
  名称：

  Synthesis of per-deuterated alkyl amines for the preparation of deuterated organic pyromellitamide gelators

  摘要：

  A general, direct and scalable synthesis of per-deuterated alkyl amines is reported, together with their incorporation into pyromellitamides, which form self-assembled gels in cyclohexane. The deuterium labelling of these gelators allows the study of the dynamic intermolecular interactions in these materials using solid-state H-2 NMR spectroscopy. Crown Copyright (C) 2013 Published by Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.03.031
• 作为产物：
  描述：

  在 ammonium hydroxide 作用下， 以 乙腈 为溶剂， 反应 2.0h， 以3.45 g的产率得到4,4,4,3,3,2,2-d₇-butanamide
  参考文献：
  名称：

  Synthesis of per-deuterated alkyl amines for the preparation of deuterated organic pyromellitamide gelators

  摘要：

  A general, direct and scalable synthesis of per-deuterated alkyl amines is reported, together with their incorporation into pyromellitamides, which form self-assembled gels in cyclohexane. The deuterium labelling of these gelators allows the study of the dynamic intermolecular interactions in these materials using solid-state H-2 NMR spectroscopy. Crown Copyright (C) 2013 Published by Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.03.031