3-(3-Perylen-3-ylphenyl)perylene | 1384579-87-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 3-(3-Perylen-3-ylphenyl)perylene
• 英文别名: 3-(3-perylen-3-ylphenyl)perylene
• CAS: 1384579-87-6
• 化学式: C₄₆H₂₆
• 分子量: 578.712
• InChiKey: HACXGBBFJSPMRR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.8
• 重原子数：
  46
• 可旋转键数：
  2
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  3-溴芘 、 1,3-苯二硼酸 生成 3-(3-Perylen-3-ylphenyl)perylene
  参考文献：
  名称：

  Photophysical properties of new bis-perylene dyads for potential upconversion use

  摘要：

  Two new bis-perylenes, BPC with a meta-disubstituted benzene linker, and BPD with a p,p'-disubstituted biphenyl linker, have been synthesized and their photophysical parameters measured. Their singlet and triplet energies decrease incrementally in the order perylene, BPC, BPD, making them ideally matched with C-60 for triplet-triplet energy transfer in sensitized photon upconversion schemes. Following photosensitization by triplet C-60, BPC exhibits strong fluorescence upconversion by triplet-triplet annihilation, indicating that these bis-perylene dyads (and the multimers that can be constructed from them) will be interesting candidates for use in organic devices such as bulk-heterojunction and dye-sensitized solar cells employing non-coherent photon upconversion. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2014.05.032

文献信息

• Photophysical properties of new bis-perylene dyads for potential upconversion use
  作者：Marcos R. Ribas、Ronald P. Steer、Ricardo Rüther

  DOI：10.1016/j.cplett.2014.05.032

  日期：2014.6

  Two new bis-perylenes, BPC with a meta-disubstituted benzene linker, and BPD with a p,p'-disubstituted biphenyl linker, have been synthesized and their photophysical parameters measured. Their singlet and triplet energies decrease incrementally in the order perylene, BPC, BPD, making them ideally matched with C-60 for triplet-triplet energy transfer in sensitized photon upconversion schemes. Following photosensitization by triplet C-60, BPC exhibits strong fluorescence upconversion by triplet-triplet annihilation, indicating that these bis-perylene dyads (and the multimers that can be constructed from them) will be interesting candidates for use in organic devices such as bulk-heterojunction and dye-sensitized solar cells employing non-coherent photon upconversion. (C) 2014 Elsevier B.V. All rights reserved.