全氟(2,5-二氮杂-2,4-己二烯) | 17227-27-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 中文名称: 全氟(2,5-二氮杂-2,4-己二烯)
• 英文名称: perfluoro-2,5-diazahexa-2,4-diene
• 英文别名: Perfluor-2,5-diazahexa-2,4-dien；N,N'-Bis(trifluoromethyl)-ethanediimidoyl difluoride；(1Z,2Z)-N,N'-bis(trifluoromethyl)ethanediimidoyl difluoride
• CAS: 17227-27-9
• 化学式: C₄F₈N₂
• 分子量: 228.045
• InChiKey: NLYNXIKSYNMTLF-IJEIGJONSA-N

物化性质

• 沸点：
  -29.4±50.0 °C(Predicted)
• 密度：
  1.62±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  全氟(2,5-二氮杂-2,4-己二烯) 以7%的产率得到
  参考文献：
  名称：

  BARNES, R. N.;CHAMBERS, R. D.;SILVESTER, M. J.;HEWITT, C. D.;KLAUKE, E., J. FLUOR. CHEM., 1984, 24, N 2, 211-218

  摘要：

  DOI：
• 作为产物：
  描述：

  N,N'-Bis-trifluormethyl-tetrafluoraethylendiamin 生成 全氟(2,5-二氮杂-2,4-己二烯)
  参考文献：
  名称：

  GROHE, K.;BRANDES, W.;HAMMANN, I., ADV. PESTIC. SCI. 4TH INT. CONGR. PESTIC. CHEM., ZURICH, JULY 24-28, 1978+

  摘要：

  DOI：

文献信息

• Reactions involving fluoride ion. Part 31. Co-oligomers of perfluoro-1-methyl-1,3-diazacyclopent-2- and -3-ene
  作者：Robert N. Barnes、Richard D. Chambers、Christopher D. Hewitt、Michael J. Silvester、Erich Klauke

  DOI：10.1039/p19850000053

  日期：——

  The fluoride ion-induced co-oligomerisations of perfluoro-1-methyl-1,3-diazacyclopent-2-and -3-ene (1) with hexafluoropropene and perfluoro-cyclobutene, -cyclopentene, and -cyclohexene are reported. Comparisons are made between these reactions of nitrogen anions and the corresponding chemistry of fluorinated carbanions.

  报道了氟离子诱导的全氟-1-甲基-1，3-二氮杂环戊-2-和-3-烯（1）与六氟丙烯和全氟-环丁烯，-环戊烯和-环己烯的共聚。在氮阴离子的这些反应与氟化碳负离子的相应化学反应之间进行了比较。
• Bis-trifluoro methyl-imino-imidazolones
  申请人：Bayer Aktiengesellschaft

  公开号：US03971804A1

  公开（公告）日：1976-07-27

  Bis-trifluoromethyl-imino-imidazolones of the formula ##SPC1## In which Each R independently is hydrogen or methyl, R.sup.2 is a radical selected from the group consisting of bridged rings; fused rings; directly linearly linked rings; rings linked through oxygen, alkylene, oxyalkylene or alkylenoxyalkylene; and substitution products of any of the foregoing with halogen, alkyl or alkoxy with 1 to 4 carbon atoms; said radicals comprising at least two carbon rings, at least one of which is non-aromatic; R.sup.3 is hydrogen or a radical selected from the group consisting of alkyl, alkenyl or alkynyl with up to 8 carbon atoms; substitution products of any of the foregoing with halogen or alkoxy with 1 to 4 carbon atoms; cycloalkyl; cycloalkyl substituted by alkyl with 1 to 4 carbon atoms; aralkyl with up to 4 carbon atoms in the alkyl part; aryl with up to 14 carbon atoms; substitution products of these aralkyl and aryl radicals with halogen, alkyl, haloalkyl or alkoxy with 1 to 4 carbon atoms; and any of the radicals listed under R.sup.2 ; each x independently is an integer from 0 to 4, Each y independently is 0 or 1 except that y must be 0 if x is 0, and Each z independently is an integer from 0 to 4, which possess acaricidal, insecticidal and fungicidal properties.

  化学式为##SPC1##的双三氟甲基亚氨基咪唑酮，其中每个R独立地是氢或甲基，R.sup.2是从桥环，融合环，直接线性连接的环，通过氧，烷基，氧烷基或烷氧基连接的环或任何这些的卤素，烷基或烷氧基的1至4个碳原子的取代产物中选择的基团；这些基团包括至少两个碳环，其中至少一个不是芳香环；R.sup.3是氢或从烷基，烯基或炔基中选择的基团，其具有最多8个碳原子；这些基团的取代产物包括卤素或1至4个碳原子的烷氧基；环烷基；被1至4个碳原子的烷基取代的环烷基；在烷基部分中具有最多4个碳原子的芳基烷基；具有最多14个碳原子的芳基；这些芳基烷基和芳基的取代产物包括卤素，烷基，卤代烷基或1至4个碳原子的烷氧基；以及在R.sup.2下列出的任何基团；每个x独立地是0到4的整数，每个y独立地是0或1，但如果x为0，则必须为0，每个z独立地是0到4的整数，具有杀螨，杀虫和杀真菌性能。
• Isomerization of perfluoro-.alpha.,.omega.-bisazomethines
  作者：Paul H. Ogden、Ronald A. Mitsch

  DOI：10.1021/ja00995a031

  日期：1967.9