N,N'-bis(4-tolyl)-N,N'-bis(4-n-butylphenyl)-1,3-phenylenediamine | 173923-36-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-bis(4-tolyl)-N,N'-bis(4-n-butylphenyl)-1,3-phenylenediamine
• 英文别名: 1-N,3-N-bis(4-butylphenyl)-1-N,3-N-bis(4-methylphenyl)benzene-1,3-diamine
• CAS: 173923-36-9
• 化学式: C₄₀H₄₄N₂
• 分子量: 552.803
• InChiKey: RHXPPGNZACCWNM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.9
• 重原子数：
  42
• 可旋转键数：
  12
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Imidazole-containing inhibitors of farnesyl protein transferase
  申请人：BRISTOL-MYERS SQUIBB COMPANY

  公开号：EP0675112A1

  公开（公告）日：1995-10-04

  Inhibition of farnesyl transferase, which is an enzyme involved in ras oncogene expression, is effected by compounds of the formula their enantiomers, diastereomers, and pharmaceutically acceptable salts, prodrugs, and solvates, wherein:    G is    G¹ is    G² is or -NR¹⁰-CH(Q¹)-;    J, K and L are each, independently, N, NR⁹, O, S or CR¹⁰ with the provisos that only one of the groups J, K and L can be O or S, and at least one of the groups J or L must be N, NR⁹, O or S to form a fused five-membered heteroring; the bond between J and K or K and L may also form one side of a phenyl ring fused to the fused five-membered heteroring;    Q is aryl;    Q¹, A¹ and A² are each, independently, H, alkyl, substituted alkyl, phenyl or substituted phenyl;    G³ is R¹¹, -C(O)OR¹¹, -C(O)NR¹¹R¹², 5-tetrazolyl, -C(O)N(R¹³)OR¹¹, -C(O)NHSO₂R¹⁴ or -CH₂OR¹¹;    G⁴ is attached at the 1, 2, 4 or 5 position and optionally substituted, at any of the available position or positions on the ring, with halo, alkyl or substituted alkyl having 1 to 20 carbon atoms, alkoxy, aryl, aralkyl, hydroxy, alkanoyl, alkanoyloxy, amino, alkylamino, dialkylamino, alkanoylamino, thiol, alkylthio, alkylthiono, alkylsulfonyl, sulfonamido, nitro, cyano, carboxy, carbamyl, N-hydroxycarbamyl, N-alkylcarbamyl, N-dialkylcarbamyl, alkoxycarbonyl, phenyl, substituted phenyl, or a combinaton of these groups;    Y and Z are each, independently, -CH₂- or -C(O)-;    R¹ - R¹⁴ are each, independently, H or alkyl having 1 to 20 carbon atoms;    R⁷, R⁸ and R¹⁴ may also be aryl or aralkyl, and R³, R⁹, R¹¹, R¹² and R¹³ may also be aralkyl;    m, n and p are each, independently, 0 or an integer from 1 to 2;    q is 0 or an integer from 1 to 4; and    the dotted line represents an optional double bond.

  抑制法尼醇转移酶是一种参与ras癌基因表达的酶，其受化合物的影响，其化合物包括其对映异构体、非对映异构体和药用可接受的盐、前药和溶剂化合物，其中： G为G¹为G²为或-NR¹⁰-CH(Q¹)-；J、K和L分别独立地为N、NR⁹、O、S或CR¹⁰，但有以下规定：J、K和L中只有一个可以是O或S，且J或L中至少有一个必须是N、NR⁹、O或S以形成融合的五元杂环；J和K之间的键或K和L之间的键也可以形成与融合的五元杂环融合的苯环的一侧；Q为芳基；Q¹、A¹和A²分别独立地为H、烷基、取代烷基、苯基或取代苯基；G³为R¹¹、-C(O)OR¹¹、-C(O)NR¹¹R¹²、5-四唑基、-C(O)N(R¹³)OR¹¹、-C(O)NHSO₂R¹⁴或-CH₂OR¹¹；G⁴附着在1、2、4或5位，并可选择地取代在环上的任何可用位置或位置，取代基为卤素、烷基或取代烷基（碳原子数为1至20）、烷氧基、芳基、芳基烷基、羟基、烷酰基、烷酰氧基、氨基、烷基氨基、二烷基氨基、烷酰氨基、硫醇基、烷基硫基、烷基硫酰基、磺酰胺基、硝基、氰基、羧基、氨基甲酰基、N-羟基氨基甲酰基、N-烷基氨基甲酰基、N-二烷基氨基甲酰基、烷氧基羰基、苯基、取代苯基或上述基团的组合；Y和Z分别独立为-CH₂-或-C(O)-；R¹-R¹⁴分别独立为H或烷基（碳原子数为1至20）；R⁷、R⁸和R¹⁴也可以是芳基或芳基烷基，R³、R⁹、R¹¹、R¹²和R¹³也可以是芳基烷基；m、n和p分别独立地为0或1至2的整数；q为0或1至4的整数；虚线表示可选的双键。
• POLYMER COMPOUND AND LIGHT-EMITTING DEVICE USING SAME
  申请人：Fukushima Daisuke

  公开号：US20120326140A1

  公开（公告）日：2012-12-27

  It is an object of the invention to provide a polymer compound that, when used in a light-emitting device, results in excellent luminance life for the obtained light-emitting device. The invention provides a polymer compound comprising a constitutional unit represented by formula (1). [In formula (1), R 1A , R 1B , R 2A , R 2B represent an unsubstituted alkyl group, R 3 and R 4 represented an unsubstituted or substituted alkyl group, an unsubstituted or substituted alkoxy group, an unsubstituted or substituted aryl group, an unsubstituted or substituted aryloxy group, an unsubstituted or substituted heterocyclic group, an unsubstituted or substituted silyl group, a halogen atom, an alkoxycarbonyl group, a carboxyl or a cyano group, and R 5 and R 6 represent an unsubstituted or substituted alkyl group, an unsubstituted or substituted alkoxy group or an unsubstituted or substituted aryl group. The letters a, b, c and d each represent an integer of 0 to 3. When multiple R 3 , R 4 , R 5 and R 6 groups are present, they may be the same or different.]

  本发明的目的是提供一种聚合物化合物，当用于发光装置时，能够为所获得的发光装置提供优异的亮度寿命。该发明提供了一种聚合物化合物，其包含由式（1）表示的构成单元。[在式（1）中，R1A、R1B、R2A、R2B表示未取代的烷基，R3和R4表示未取代或取代的烷基，未取代或取代的烷氧基，未取代或取代的芳基，未取代或取代的芳氧基，未取代或取代的杂环基，未取代或取代的硅基，卤素原子，烷氧羰基，羧基或氰基，R5和R6表示未取代或取代的烷基，未取代或取代的烷氧基或未取代或取代的芳基。字母a、b、c和d分别表示0到3的整数。当存在多个R3、R4、R5和R6基团时，它们可以相同或不同。]
• m-Phenylenediamine derivatives and electrophotosensitive material using the same
  申请人：MITA INDUSTRIAL CO. LTD.

  公开号：EP0687668A2

  公开（公告）日：1995-12-20

  The present invention provides a m-phenylenediamine derivative which is novel as an electric charge transferring material, particularly hole transferring material, and an electrophosensitive material having a high sensitivity. This derivative includes a compound represented by the general formula (1) below or by formula (2) or (3) of the specification. Regarding the electrophotosensitive material, a photosensitive layer containing the m-phenylenediamine derivative as the hole transferring material is provided on a conductive substrate: wherein R1 and R2 are the same or different and each indicates a hydrogen atom or an alkyl group which may have one or more substituents; and R3 and R4 are same or different and each indicates a straight-chain or branched alkyl group having 3 to 5 carbon atoms; provided that R1, R2, R3 and R4 are not the same alkyl groups, simultaneously.

  本发明提供了一种间苯二胺衍生物，它作为电荷转移材料，特别是空穴传输材料和具有高灵敏度的电敏感材料，具有新颖性。这种衍生物包括以下通式（1）或本说明书式（2）或（3）所代表的化合物。关于电致发光材料，在导电基底上设置含有间苯二胺衍生物作为空穴传输材料的光敏层： 其中，R1 和 R2 相同或不同，且各自表示氢原子或可具有一个或多个取代基的烷基；R3 和 R4 相同或不同，且各自表示具有 3 至 5 个碳原子的直链或支链烷基；条件是 R1、R2、R3 和 R4 同时不是相同的烷基。
• POLYMER COMPOUND AND LIGHT EMITTING DEVICE USING THE SAME
  申请人：FUKUSHIMA Daisuke

  公开号：US20110187266A1

  公开（公告）日：2011-08-04

  A polymer compound that, when used for fabrication of a light emitting device, results in an excellent luminance lifetime for the obtained light emitting device. A polymer compound comprising a constitutional unit represented by formula (1). (In the formula, R 1 and R 2 each independently represent an unsubstituted alkyl group. R 3 and R 4 each independently represent a group other than an unsubstituted alkyl group. R 5 and R 6 each independently represent an unsubstituted or substituted alkyl, unsubstituted or substituted alkoxy or unsubstituted or substituted aryl group. The letters a and b each independently represent an integer of 0-4. The letters c and d each independently represent an integer of 0-3. When multiple R 3 , R 4 , R 5 and R 6 groups are present, they may be the same or different.)
• POLYMER COMPOUND HAVING CARBON CLUSTER STRUCTURE AND ORGANIC DEVICE USING SAME
  申请人：Tanaka Shin-Ya

  公开号：US20130270545A1

  公开（公告）日：2013-10-17

  A polymer compound, is provided in which at least a part of repeating units has a group containing a carbon cluster structure. The polymer compound preferably one or more, more preferably two or more, units selected from an arylene unit, a heteroarylene unit and an aromatic amine unit, as repeating units.