3-sulfobutyl-1-(3-propyltriethoxysilane)imidazolium hydrogen sulfate | 1259925-01-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 3-sulfobutyl-1-(3-propyltriethoxysilane)imidazolium hydrogen sulfate
• 英文别名: (3-chloropropyl)triethoxysilane
• CAS: 1259925-01-3
• 化学式: C₁₆H₃₃N₂O₆SSi*HO₄S
• 分子量: 506.671
• InChiKey: YDUNTQNDTISJPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.89
• 重原子数：
  31.0
• 可旋转键数：
  15.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  168.3
• 氢给体数：
  2.0
• 氢受体数：
  9.0

反应信息

• 作为产物：
  描述：

  3-氯丙基三乙氧基硅烷 在 sodium ethanolate 作用下， 以 乙醇 为溶剂， 反应 50.0h， 生成 3-sulfobutyl-1-(3-propyltriethoxysilane)imidazolium hydrogen sulfate
  参考文献：
  名称：

  铜掺杂介孔二氧化硅负载的双酸性离子液体可作为Biginelli反应的高效协同重用催化剂

  摘要：

  制备了一系列掺杂有铜物质的MCM-41负载型官能化离子液体，对其进行了表征和评估，作为Biginelli反应的催化剂。这些负载型离子液体大多数在反应中表现良好，尤其是多官能铜配位的MCM-41负载型多相催化剂（0.5）IL-TiCl 5 @ [受电子邮件保护]（15）和（0.5）IL-HSO 4 @ [受电子邮件保护] ]（15）。催化试验表明，（0.5）IL-HSO 4@ [受电子邮件保护]（15）是Biginelli反应中最好的和强大的催化剂，用于制备3,4-二氢嘧啶酮，产率高至优异。通过过滤可以很容易地将催化剂从反应混合物中分离出来，并在六个连续的循环中重复使用，而不会明显降低催化活性。

  DOI：

  10.1016/j.molliq.2018.04.121
• 作为试剂：
  描述：

  果糖 在 3-sulfobutyl-1-(3-propyltriethoxysilane)imidazolium hydrogen sulfate 作用下， 以 二甲基亚砜 为溶剂， 反应 2.0h， 以99%的产率得到5-羟甲基糠醛
  参考文献：
  名称：

  Functionalized ionic liquids supported on silica as mild and effective heterogeneous catalysts for dehydration of biomass to furan derivatives

  摘要：

  A series of functional ionic liquid supported silica nanoparticles with different acidity (ILs/Si02) have been prepared by covalent bonds using novel, non-toxic ethanol as solvent. Compared with using toluene or acetonitrile as solvent in traditional prepared method, the process represents a green, environmental friendly route to synthesize supported functional ionic liquid catalysts (SFILCs). These SFILCs, with the benefits of ionic liquid and the advantages of immobilization, were first systematically utilized in biomass dehydration reactions and proved to be efficient heterogeneous catalysts for the preparation of furan derivatives from various carbohydrates. However, the supported dual acidic functional ionic liquid catalyst (3-sulfobuty1-1-(3-propyltriethoxysilane) imidazolium hydrogen sulfate) was found to be more active and selective than other ILs/SiO2 and the conversion of fructose, glucose, xylose, sucrose, cellobiose was up to 99, 96, 94, 76 and 99%. Moreover, the reducing sugar (TRS) yield of microcrystalline cellulose dehydration was up to 77%. (C)2015 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2015.09.020

文献信息

• MOR zeolite supported Brønsted acidic ionic liquid: an efficient and recyclable heterogeneous catalyst for ketalization
  作者：Zhang-Min Li、Yan Zhou、Duan-Jian Tao、Wei Huang、Xiang-Shu Chen、Zhen Yang

  DOI：10.1039/c4ra00092g

  日期：——

  In order to widen the application of ionic liquids as efficient and renewable heterogeneous catalysts, supported ionic liquids (SILs) have received considerable attention.

  为了扩大离子液体作为高效可再生的异质催化剂的应用，支持的离子液体（SILs）受到了广泛关注。
• A magnetic nanoparticle supported dual acidic ionic liquid: a “quasi-homogeneous” catalyst for the one-pot synthesis of benzoxanthenes
  作者：Qiang Zhang、Hong Su、Jun Luo、Yunyang Wei

  DOI：10.1039/c1gc16031a

  日期：——

  A novel magnetic nanoparticle supported dual acidic ionic liquid catalyst was synthesized by anchoring 3-sulfobutyl-1-(3-propyltriethoxysilane) imidazolium hydrogen sulfate onto the surface of silica-coated Fe3O4 nanoparticles. Due to the combination of nano-support features and flexible imidazolium linkers, it acted as a “quasi-homogeneous” catalyst to effectively catalyze the one-pot synthesis of

  新颖的磁性 纳米粒子 支持双酸性 离子液体 催化剂通过将3-磺基丁基-1-（3-丙基三乙氧基硅烷）咪唑硫酸氢盐锚定在二氧化硅包覆的Fe 3 O 4表面上来合成 纳米粒子。由于纳米载体特征和灵活的咪唑鎓连接基的组合​​，它充当了“准均相”催化剂，通过三组分缩合反应有效催化一锅合成苯并氧杂蒽。二甲酮 和 醛 和 2-萘酚 在下面 溶剂无条件。更重要的是催化剂 可以很容易地被外部磁铁回收，并可以重复使用六次，而不会显着降低催化活性。
• Brønsted–Lewis dual acidic ionic liquid immobilized on mesoporous silica materials as an efficient cooperative catalyst for Mannich reactions
  作者：Hong Bo Wang、Nan Yao、Long Wang、Yu Lin Hu

  DOI：10.1039/c7nj02541f

  日期：——

  Novel mesoporous silica supported ILs have been prepared and successfully applied as a heterogeneous catalyst in Mannich reactions. The excellent recyclability of the supported catalyst, mild reaction conditions, good to excellent yields, low catalyst loading, and operational simplicity are the important features of this methodology.

  已经制备了新型介孔二氧化硅负载的IL，并将其成功用作曼尼希反应中的多相催化剂。该方法的重要特点是负载的催化剂具有出色的可回收性，温和的反应条件，良好的产率至极好的产率，低的催化剂负载量以及操作简便性。
• Magnetic, Acidic, Ionic Liquid-Catalyzed One-Pot Synthesis of Spirooxindoles
  作者：Ali Khalafi-Nezhad、Somayeh Mohammadi

  DOI：10.1021/co400080z

  日期：2013.9.9

  Magnetic, supported, acidic ionic liquid was synthesized and identified as an efficient catalyst for the one-pot synthesis of novel spirooxindole derivatives at mild conditions and in good yields. Three component reaction of wide variety of substituted isatins, 1,3-dimethyl-2-amino uracil, and barbituric acid, thiobarbituric acid, and dimedon as 1,3-dicarbonyl compounds gives the target compounds.

  合成了磁性负载型酸性离子液体，并确定其为在温和条件下以高收率一锅合成新型螺氧杂吲哚衍生物的有效催化剂。各种取代的靛红，1，3-二甲基-2-氨基尿嘧啶和巴比妥酸，硫代巴比妥酸和二聚体作为1，3-二羰基化合物的三组分反应得到目标化合物。该方法的关键特征是操作简便，成本低，产率高，环境友好，广泛的适用性和可重复使用性以及使用外磁体容易回收催化剂。
• A silica gel supported dual acidic ionic liquid: an efficient and recyclable heterogeneous catalyst for the one-pot synthesis of amidoalkyl naphthols
  作者：Qiang Zhang、Jun Luo、Yunyang Wei

  DOI：10.1039/c0gc00472c

  日期：——

  acidic ionic liquid catalyst was prepared via anchoring 3-sulfobutyl-1-(3-propyltriethoxysilane) imidazolium hydrogen sulfate onto silica gel by covalent bonds. The novel immobilized acidic ionic liquid effectively catalyzed the one-pot synthesis of amidoalkyl naphthols by the multicomponent condensation of aldehydes with 2-naphthol and amides under solvent-free conditions. Moreover, the catalyst could

  负载型双酸性离子液体 催化剂是通过锚定准备的3-磺基丁基-1-（3-丙基三乙氧基硅烷）咪唑鎓 硫酸氢通过共价键键合到硅胶上 新型固定化酸性离子液体通过醛与乙醛的多组分缩合有效催化酰胺基烷基萘的一锅合成。2-萘酚在无溶剂条件下使用酰胺。而且，催化剂 可以回收六次而不会造成重大损失 催化活性。