[4-[(4-Phenyldiazenylnaphthalen-1-yl)diazenyl]phenyl] 2-methylprop-2-enoate | 1263797-12-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [4-[(4-Phenyldiazenylnaphthalen-1-yl)diazenyl]phenyl] 2-methylprop-2-enoate
• 英文别名: [4-[(4-phenyldiazenylnaphthalen-1-yl)diazenyl]phenyl] 2-methylprop-2-enoate
• CAS: 1263797-12-1
• 化学式: C₂₆H₂₀N₄O₂
• 分子量: 420.47
• InChiKey: WSUYOTNVFLJLFH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  32
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  75.7
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  甲基丙烯酰氯 、 分散橙13 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以75%的产率得到[4-[(4-Phenyldiazenylnaphthalen-1-yl)diazenyl]phenyl] 2-methylprop-2-enoate
  参考文献：
  名称：

  Second- and Third-Order Nonlinearities of Novel Push−Pull Azobenzene Polymers

  摘要：

  In this work, the second- and third-order nonlinear optical response of spin-deposited thin films of three different push pull side chain azobenzene polymers is investigated by the second- and third-harmonic Maker fringes techniques using 30 Ps laser pulses at a fundamental wavelength of 1064 nm. Measurements were carried out before and after aligning the chromophores by corona poling of the films, while different polarization configurations have been utilized. Strong dependence of the response upon the structure of the systems has been found, which is related to the different charge transfer within the molecules. The reported findings are compared with already published results.

  DOI：

  10.1021/jp109936t

文献信息

• Second- and Third-Order Nonlinearities of Novel Push−Pull Azobenzene Polymers
  作者：Hasnaa El Ouazzani、Konstantinos Iliopoulos、Mindaugas Pranaitis、Oksana Krupka、Vitaliy Smokal、Aleksey Kolendo、Bouchta Sahraoui

  DOI：10.1021/jp109936t

  日期：2011.3.10

  In this work, the second- and third-order nonlinear optical response of spin-deposited thin films of three different push pull side chain azobenzene polymers is investigated by the second- and third-harmonic Maker fringes techniques using 30 Ps laser pulses at a fundamental wavelength of 1064 nm. Measurements were carried out before and after aligning the chromophores by corona poling of the films, while different polarization configurations have been utilized. Strong dependence of the response upon the structure of the systems has been found, which is related to the different charge transfer within the molecules. The reported findings are compared with already published results.