(MeCN)Cu(Piv)4Cu(MeCN) | 1135444-63-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (MeCN)Cu(Piv)4Cu(MeCN)
• 英文别名: (acetonitrile)Cu(pivalate)4Cu(acetonitrile)
• CAS: 1135444-63-1
• 化学式: C₂₄H₄₂Cu₂N₂O₈
• 分子量: 613.698
• InChiKey: DDDUTTXLOLQUMK-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  copper(II) dipivaloate 、 乙腈 以 乙腈 为溶剂， 生成 (MeCN)Cu(Piv)4Cu(MeCN)
  参考文献：
  名称：

  Influence of the nature of organic components in dinuclear copper(II) pivalates on the composition of thermal decomposition products

  摘要：

  Tetrabridged dinuclear complexes ((2-NH2)C5H4N)(2)Cu-2(mu(2)-OOCCMe3)(4) (2 center dot C6H6) and ((3-NH2)C5H4N)(2)Cu-2 (mu(2)-OOCCMe3)(4) (3) and the cocrystallization product ((4-NMe2)C5H4N)(2)Cu(eta(2)-OOCCMe3)(2)center dot 2((4-NMe2)C5H4N)(2)Cu-2(mu(2)-OOCCMe3)(4) (4) were synthesized by the reaction of the polymer [Cu(OOCCMe3)(2)](n) (1) with aminopyridine ligands (L) of different nature (Cu: L = 1:1) in C6H6. The solid-state thermal decomposition of these compounds was studied by differential scanning calorimetry and thermogravimetry, and their electrochemical behavior was investigated by cyclic voltammetry. All newly synthesized complexes were studied by X-ray diffraction, the magnetic properties of the complexes were investigated, and ESR measurements were performed. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.02.021