DBPC | 1351955-00-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: DBPC
• 英文别名: 3-(3,6-Dibromocarbazol-9-yl)-1,10-phenanthroline；3-(3,6-dibromocarbazol-9-yl)-1,10-phenanthroline
• CAS: 1351955-00-4
• 化学式: C₂₄H₁₃Br₂N₃
• 分子量: 503.195
• InChiKey: RVJUFOQNNAJKKS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  29
• 可旋转键数：
  1
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  30.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  NPC 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 2.0h， 以85%的产率得到DBPC
  参考文献：
  名称：

  Synthesis and applications of 3,6-carbazole-based conjugated side-chain copolymers containing complexes of 1,10-phenanthroline with Zn(II), Cd(II) and Ni(II) for dye-sensitized solar cells

  摘要：

  Three novel donor-acceptor polymeric metal complexes based on polycarbazole containing complexes of 1,10-phenanthroline with Zn(II), Cd(II) and Ni(II) have been synthesized by the Ullmann reaction and characterized by gel permeation chromatography, FT-IR, UV-visible absorption and photoluminescence spectroscopy, cyclic voltammetry and elemental analysis. The application of these organometallic polymers in fabricated dye-sensitized solar cells has been studied. The solar cells exhibited good device performance with a power conversion efficiency of up to 0.44%, under simulated air mass 1.5 G solar irradiation. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.07.007