Heptadecan-9-amine hydrochloride | 5429-71-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Heptadecan-9-amine hydrochloride
• 英文别名: heptadecan-9-amine;hydrochloride
• CAS: 5429-71-0
• 化学式: C17H38ClN
• 分子量: 291.9
• InChiKey: QEURDSQISWCHGQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  19
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  27.6
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• Organosilicon compound
  申请人：Chisso Corporation

  公开号：EP1849788A1

  公开（公告）日：2007-10-31

  There is provided a silicon compound represented by Formula (1) : wherein A is a group represented by Formula, (2-1): wherein Z1 is an alkylene having 3 to 20 carbon atoms, and arbitrary -CH2- in this alkylene may be replaced by -O-; R3 is hydrogen, an alkyl having 1 to 20 carbon atoms, an aryl having 6 to 20 carbon atoms, or an arylalkyl having 7 to 20 carbon atoms; R4 is an alkyl having 1 to 20 carbon atoms, an aryl having 6 to 20 carbon atoms, or an arylalkyl having 7 to 20 carbon atoms; and X1 is a halogen, and a process for producing said silicon compound represented by Formula (1-1).

  提供了一种由式（1）表示的硅化合物： 其中 A 是由式（2-1）表示的基团： 其中 Z1 是具有 3 至 20 个碳原子的亚烷基，该亚烷基中任意的-CH2-可被-O-取代； R3 是氢、具有 1 至 20 个碳原子的烷基、具有 6 至 20 个碳原子的芳基或具有 7 至 20 个碳原子的芳烷基； R4 是具有 1 至 20 个碳原子的烷基、具有 6 至 20 个碳原子的芳基或具有 7 至 20 个碳原子的芳烷基； X1 是卤素，以及 生产式（1-1）所代表的硅化合物的工艺。
• Silicon compounds
  申请人：Yamahiro Mikio

  公开号：US20050049381A1

  公开（公告）日：2005-03-03

  The present invention relates to a novel silicon compound characterized by having a polymerization-initiating ability to polymerizable monomers and a polymer obtained using the same. Provided is a so-called organic-inorganic composite material of cage type silsesquioxane in which an organic substituent is bonded to a silicon atom and an organic polymer. A preparing method thereof is mixing with an organic polymer or copolymerization making use of a polymerizable functional group of cage type silsesquioxane. However, it is considered to be very difficult to evenly disperse an inorganic component in an organic polymer in either method and maintain characteristics thereof. The present invention provides a silicon compound represented by Formula (1): in Formula (1), A 1 is a group having a polymerization-initiating ability to a monomer; R 1 is alkyl having 2 to 10 carbon atoms; in these alkyls, at least one hydrogen may be replaced by halogen; one —CH 2 — may be replaced by —O—; one hydrogen may be replaced by an aromatic group or an alicyclic group; this aromatic group or alicyclic group may have a substituent; R 2 and R 3 are independently alkyl having 1 to 8 carbon atoms, phenyl or cyclohexyl; n is an integer of 2 to 30; e is 0 or 1; a is an integer of 1 to 2 n ; b is an integer of 0 to (2 n −1); c is an integer of 0 to (2 n −1); and the total of a, b and c is 2 n . The preferred examples of A 1 are a group having halogenated alkylphenyl, a group having an MgBr group and a group having a dithiocarbamate group. If initiating the polymerization of, for example, an acrylic monomer with this silsesquioxane derivative acting as a starting point, a very homogeneous organic-inorganic composite material is obtained without causing coagulation of silsesquioxane, and therefore problems in conventional methods are solved.

  本发明涉及一种新型硅化合物，其特点是对可聚合单体具有聚合引发能力，以及使用该化合物获得的聚合物。本发明提供了一种所谓的有机-无机复合材料，即有机取代基与硅原子键合的笼型硅倍半氧烷和有机聚合物。其制备方法是与有机聚合物混合或利用笼型硅倍半氧烷的可聚合官能团进行共聚。然而，无论采用哪种方法，都很难将无机成分均匀分散在有机聚合物中并保持其特性。 本发明提供了一种由式（1）表示的硅化合物： 式（1）中，A 1 是对单体具有聚合引发能力的基团；R 1 是具有 2 至 10 个碳原子的烷基；在这些烷基中，至少有一个氢可以被卤素取代；一个 -CH 2 - 可被-O-取代；一个氢可被芳香基团或脂环基团取代；该芳香基团或脂环基团可带有取代基；R 2 和 R 3 独立地为具有 1 至 8 个碳原子的烷基、苯基或环己基； n 为 2 至 30 的整数； e 为 0 或 1； a 为 1 至 2 的整数 n b 是 0 至（2 n -1）的整数；c 是 0 至（2 n n -1）的整数；a、b 和 c 的总和为 2 n .A 1 是具有卤代烷基苯基的基团、具有硼酸镁基团的基团和具有二硫代氨基甲酸酯基团的基团。 如果以这种硅倍半氧烷衍生物为起点，启动丙烯酸单体等的聚合反应，就可以得到非常均匀的有机-无机复合材料，而不会引起硅倍半氧烷的凝结，从而解决了传统方法中存在的问题。
• Silicon compound
  申请人：Chisso Corporation

  公开号：EP1650214B1

  公开（公告）日：2009-11-04
• SILICON COMPOUND
  申请人：JNC Corporation

  公开号：EP1550664B1

  公开（公告）日：2012-06-27
• Organosilicon compound
  申请人：Chisso Corporation

  公开号：EP1686133B1

  公开（公告）日：2008-08-20