1-<4'-Fluor-benzyl>-3.4-dihydro-isochinolin | 46883-45-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: 1-<4'-Fluor-benzyl>-3.4-dihydro-isochinolin
• CAS: 46883-45-8
• 化学式: C₁₆H₁₄FN
• 分子量: 239.292
• InChiKey: FKELOVZBJUZKQH-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  1-<4'-Fluor-benzyl>-3.4-dihydro-isochinolin 在 lithium aluminium tetrahydride 作用下， 以 乙醚 、 乙醇 为溶剂， 反应 12.0h， 生成
  参考文献：
  名称：

  Mechanism of formation of doubly charged fragments from bis-benzyltetrahydroisoquinolines under electron impact

  摘要：

  AbstractSome bis‐benzyltetrahydroisoquinolines [α,α′‐di‐N,N‐(1‐benzyl‐1,2,3,4‐tetrahydroisoquinoline)‐p‐xylene and various substituted analogues] give rise to very abundant doubly charged fragment ions under electron impact, corresponding to the loss of the two benzyl groups. Substituent effects, ionization and appearance energy measurements and metastable transitions show that these doubly charged ions are formed (at least in part) from singly charged precursors by a heterolytic cleavage (charge separation).

  DOI：

  10.1002/oms.1210151105