(4R,5R)-2,2-Dimethyl-4,5-bis-(naphthalen-1-ylsulfanylmethyl)-[1,3]dioxolane | 591208-48-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (4R,5R)-2,2-Dimethyl-4,5-bis-(naphthalen-1-ylsulfanylmethyl)-[1,3]dioxolane
• 英文别名: (4R,5R)-2,2-dimethyl-4,5-bis(naphthalen-1-ylsulfanylmethyl)-1,3-dioxolane
• CAS: 591208-48-9
• 化学式: C₂₇H₂₆O₂S₂
• 分子量: 446.634
• InChiKey: OKFMYYRNONGGKL-ZEQRLZLVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  31
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  69.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (4R,5R)-2,2-Dimethyl-4,5-bis-(naphthalen-1-ylsulfanylmethyl)-[1,3]dioxolane 在 盐酸 作用下， 以 甲醇 为溶剂， 生成 (2R,3R)-1,4-Bis-(naphthalen-1-ylsulfanyl)-butane-2,3-diol
  参考文献：
  名称：

  Asymmetric Epoxidation of Aldehydes Catalyzed by New C2-Symmetrical Chiral Sulfide

  摘要：

  Asymmetric synthesis of chiral epoxides from various aldehydes with benzyl bromide was investigated using new C-2-symmetrical chiral sulfides, which were readily prepared from (R,R)-tartaric acid.

  DOI：

  10.3987/com-02-9520
• 作为产物：
  描述：

  1-奈硫酚 、 (-)-1,4-二-O-甲苯磺酰基-2,3-O-异亚丙基-L-苏糖醇 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 生成 (4R,5R)-2,2-Dimethyl-4,5-bis-(naphthalen-1-ylsulfanylmethyl)-[1,3]dioxolane
  参考文献：
  名称：

  Asymmetric Epoxidation of Aldehydes Catalyzed by New C2-Symmetrical Chiral Sulfide

  摘要：

  Asymmetric synthesis of chiral epoxides from various aldehydes with benzyl bromide was investigated using new C-2-symmetrical chiral sulfides, which were readily prepared from (R,R)-tartaric acid.

  DOI：

  10.3987/com-02-9520

文献信息

• Asymmetric Epoxidation of Aldehydes Catalyzed by New C2-Symmetrical Chiral Sulfide
  作者：Miyuki Ishizaki、Osamu Hoshino

  DOI：10.3987/com-02-9520

  日期：——

  Asymmetric synthesis of chiral epoxides from various aldehydes with benzyl bromide was investigated using new C-2-symmetrical chiral sulfides, which were readily prepared from (R,R)-tartaric acid.