[HgI2(N,N'-bis(3-pyridylmethyl)thiourea)]2 | 866395-88-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯并吡啶类
• 英文名称: [HgI2(N,N'-bis(3-pyridylmethyl)thiourea)]2
• CAS: 866395-88-2
• 化学式: C₂₆H₂₈Hg₂I₄N₈S₂
• 分子量: 1425.49
• InChiKey: PJZQCGCCKRBRIX-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  mercury(II) iodide 、 1,3-双(3-吡啶甲基)-2-硫脲 以 四氢呋喃 、 甲醇 为溶剂， 以20%的产率得到[HgI2(N,N'-bis(3-pyridylmethyl)thiourea)]2
  参考文献：
  名称：

  The syntheses, crystal structures and optical limiting effects of transition metal adducts bridged by bipyridyl-based ligands

  摘要：

  Two novel compounds [HgI2(bPt)](2) (1) and [MnCl2(bpt)(2)](n)center dot 2CH(3)OH (2) (bpt = N,N'-bis(3-pyridylmethyl)thiourea), have been synthesized via the self-assembly reaction in solution. Complex I possesses a two-dimensional supramolecular network formed by hydrogen bonds among repeating [HgI2(bpt)](2) dimeric units. Complex 2 is a one-dimensional coordination polymer containing uniform -MnCl2-(bpt)(2)-MnCl2-(bpt)(2)- double chain. Their limiting thresholds were determined to be 1.0 J cm(-2) for 1 and 0.7 J cm(-2) for 2 and the results testified that the skeletal structure and constituted metal nuclearity have a strong impact on the NLO properties of the complexes. (C) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.02.012